Docking of tetra-methyl zirconium to the surface of silica: a well-defined pre-catalyst for conversion of CO2 to cyclic carbonates.
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DOI: 10.1039/c9cc07383c
Abstract: The metal complex (Zr(CH3)4(THF)2) has been fully synthesized, characterized and grafted onto partially dehydroxylated silica to give two surface species [([triple bond, length as m-dash]Si-O-)Zr(CH3)3(THF)2] (minor) and [([triple bond, length as m-dash]Si-O-)2Zr(CH3)2(THF)2] (major) which have… read more here.
Keywords: conversion co2; surface; co2 cyclic; ch3 thf ... See more keywords