Synthesis of rhenacyclopentadienes and η2:η2-diyne complexes from a labile dirhenium carbonyl and π-conjugated 1,7-octadiynes: Structural and photophysical characterization
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.12.003
Abstract: Abstract A series of dirhenium carbonyl compounds containing π-conjugated diyne ligands and symmetrical 2,5-bis(aryl)rhenacyclopentadienes has been synthesized by reaction of [Re2(CO)8(CH3CN)2] and 1,8-bis(aryl)-1,7-octadiyne derivatives [aryl = 2-thienyl (a), 2-pyridyl (b), 2-quinolyl (c) and 9-phenanthrenyl (d)]. We found… read more here.
Keywords: diyne complexes; re2 ch3cn; dirhenium carbonyl; bis aryl ... See more keywords
The cocatalyst roles of three anionic Cd(II) porphyrinic metal-organic frameworks in the photocatalytic CO2 reduction to CO process carried out in Ru(bpy)3Cl2/CH3CN/H2O/Triethylamine or triethanolamine system
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Solid State Chemistry"
DOI: 10.1016/j.jssc.2020.121690
Abstract: Abstract Three 3D, anionic Cd(II) porphyrinic metal-organic frameworks (PMOFs), 1(3.5:1)-2d-120 ([Cd3·2(H2TCPP)2][(CH3)2NH2]1.6), its Li+-exchanged product (e.g. Li+-1-120, formula: [Cd3·2(H2TCPP)2]Li1.6) and 1(10:1)-4d-120 ([Cd3·7H2TCPP)2][(CH3)2NH2]0.6) were synthesized, all of which have the same PXRD pattern. Their VB and CB… read more here.
Keywords: bpy 3cl2; ch3cn; co2 reduction; system ... See more keywords
Steric and Lewis Basicity Influence of the Second Coordination Sphere on Electrocatalytic CO2 Reduction by Manganese Bipyridyl Complexes.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02586
Abstract: This study aims to provide a greater insight into the balance between steric (bpy vs (Ph)2bpy vs mes2bpy ligands) and Lewis basic ((Ph)2bpy vs (MeOPh)2bpy vs (MeSPh)2bpy ligands) influence on the efficiencies of the protonation-first… read more here.
Keywords: ch3cn; protonation first; based precatalyst; reduction ... See more keywords
Exceptional Structural Compliance of the B12F122- Superweak Anion.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00051
Abstract: The single-crystal X-ray structures, thermogravimetric analyses, and/or FTIR spectra of a series of salts of the B12F122- anion and homoleptic Ag(L)n+ cations are reported (L = CH2Cl2, n = 2; L = PhCH3, n =… read more here.
Keywords: ch3cn; superweak anion; ag2 ch3cn; structural compliance ... See more keywords
Fluorene-decorated Ir(III) complexes: synthesis, photophysics and tunable triplet excited state properties in aggregation.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01592g
Abstract: Two new heteroleptic cationic Ir(III) complexes bearing benzothiazole and pyridine motifs on fluorene groups were synthesized and characterized. Complexes Ir1 and Ir2 exhibit 1π,π* transitions below 430 nm, with broad but weak metal-to-ligand and ligand-to-ligand… read more here.
Keywords: ch3cn; triplet excited; iii complexes; iii ... See more keywords
Photolysis of acetonitrile in a water-rich ice as a source of complex organic molecules: CH3CN and H2O:CH3CN ices
Sign Up to like & getrecommendations! Published in 2021 at "Astronomy and Astrophysics"
DOI: 10.1051/0004-6361/202039695
Abstract: Context. Many C-, O-, and H-containing complex organic molecules (COMs) have been observed in the interstellar medium (ISM) and their formation has been investigated in laboratory experiments. An increasing number of recent detections of large… read more here.
Keywords: ch3cn; water; complex organic; organic molecules ... See more keywords