Catalytic oxidation of CH4 into CH3OH using C24N24-supported single-atom catalyst
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Modeling"
DOI: 10.1007/s00894-021-04971-2
Abstract: Methanol is a promising source that can replace non-renewable petroleum energy. Therefore, it is of great importance to oxidize the methane into methanol because methane is not easy to transport although its huge reserves. The… read more here.
Keywords: ch3oh; oxidation; atom catalyst; single atom ... See more keywords
Synthesis, characterization, and phase transition of an inorganic–organic hybrid compound, [(3-nitroanilinium+)(18-crown-6)][IO4−](CH3OH)
Sign Up to like & getrecommendations! Published in 2017 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2016.07.013
Abstract: Abstract A novel inorganic–organic hybrid supramolecular compound, [(3-nitroanilinium+)(18-crown-6)][IO4−](CH3OH) (1), was discovered as phase-transition materials displaying dielectric anomalous behaviors. The yellow block crystal formed by N–H···O hydrogen bonding that made contact through the cavity of 18-crown-6… read more here.
Keywords: ch3oh; transition; phase transition; inorganic organic ... See more keywords
Enhanced CO2 photocatalytic conversion into CH3OH over visible‐light‐driven Pt nanoparticle-decorated mesoporous ZnO–ZnS S-scheme heterostructures
Sign Up to like & getrecommendations! Published in 2021 at "Ceramics International"
DOI: 10.1016/j.ceramint.2021.06.086
Abstract: Abstract In the present contribution, the design and fabrication of Pt nanoparticle-decorated mesoporous ZnO–ZnS heterostructures were described and used effectively for photocatalytic CO2 conversion to yield CH3OH. TEM images of the mesoporous Pt/ZnS–ZnO heterostructure demonstrated… read more here.
Keywords: zns zno; mesoporous zno; zns; zno zns ... See more keywords
Mechanistic insight into formaldehyde hydroformylation catalyzed by rhodium complexes: A theoretical and experimental study
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2021.04.021
Abstract: Abstract The aldehyde hydroformylation is of critical importance for synthesis of higher aldehydes and polyhydric alcohols, but the reaction mechanism has not been clearly resolved in the existing literature. In this paper, we have established… read more here.
Keywords: hydroformylation; experimental study; formaldehyde hydroformylation; mechanism ... See more keywords
Titania-Modified Silver Electrocatalyst for Selective CO2 Reduction to CH3OH and CH4 from DFT Study
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.7b03314
Abstract: Electrochemical reduction of CO2 to produce useful fuels and chemicals is one of the attractive means to reuse CO2. Herein, we constructed a (TiO2)3/Ag(110) model electrocatalyst and examined CO2 reduction pathways. Our results show that… read more here.
Keywords: reduction; co2 reduction; ch3oh; titania modified ... See more keywords
Effect of Multilayer Methanol and Water in Methanol Photochemistry on TiO2
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Physical Chemistry C"
DOI: 10.1021/acs.jpcc.7b04224
Abstract: We have conducted a series of temperature-programmed desorption (TPD) experiments to study the photoinduced reactions of methanol (CH3OH) on a rutile(R)-TiO2(110) surface with 355 nm light. Products formaldehyde (CH2O) and water (H2O) have been detected.… read more here.
Keywords: tio2; ch3oh; methanol; water ... See more keywords
Regulating the Spin State of Single Noble Metal Atoms by Hydroxyl for Selective Dehydrogenation of CH4 Direct Conversion to CH3OH.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c25203
Abstract: The key scientific challenge for methane (CH4) direct conversion to methanol (CH3OH) is considered to be the prevention of overoxidation of target products, which is restrained by the difficulty in the well-controlled process of selective… read more here.
Keywords: ch4; spin state; spin; ch3oh ... See more keywords
Why and How Carbon Dioxide Conversion to Methanol Happens on Functionalized Semiconductor Photoelectrodes.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b09946
Abstract: Functionalization of semiconductor electrode surfaces with adsorbed 2-pyridinide (2-PyH-*) has been postulated to enable selective CO2 photoelectroreduction to CH3OH. This hypothesis is supported by recent estimates of sufficient 2-PyH-* lifetimes and low barriers for hydride… read more here.
Keywords: ch3oh; ch2; semiconductor; carbon dioxide ... See more keywords
Effect of ammonia and water molecule on OH + CH3OH reaction under tropospheric condition
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DOI: 10.1038/s41598-021-90640-6
Abstract: The rate coefficients for OH + CH3OH and OH + CH3OH (+ X) (X = NH3, H2O) reactions were calculated using microcanonical, and canonical variational transition state theory (CVT) between 200 and 400 K based on potential energy surface constructed using CCSD(T)//M06-2X/6-311++G(3df,3pd).… read more here.
Keywords: ammonia water; ch3oh; reaction; molecule ch3oh ... See more keywords
A new class of nickel(II) oxyquinoline-bipyridine complexes as potent anticancer agents induces apoptosis and autophagy in A549/DDP tumor cells through mitophagy pathways.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00669c
Abstract: A new class of nickel(II) oxyquinoline-bipyridine complexes, namely, [Ni(La1)2(Lb6)] (Ni1), [Ni(La1)2(Lb2)] ·CH3OH (Ni2), [Ni(La7)2(Lb11)]·2H2O (Ni3), [Ni(La1)2(Lb9)] (Ni4), [Ni(La1)2(Lb8)] (Ni5), [Ni(La2)2(Lb1)] (Ni6), [Ni(La2)2(Lb6)]·CH3OH (Ni7), [Ni(La2)2(Lb11)]·CH3OH (Ni8), [Ni(La2)2(Lb3)] (Ni9), [Ni(La2)2(Lb2)]·CH3OH (Ni10), [Ni(La2)2(Lb5)]·CH3OH (Ni11), [Ni(La2)2(Lb7)] (Ni12), [Ni(La3)2(Lb2)] (Ni13),… read more here.
Keywords: a549 ddp; bipyridine; la2; ch3oh ... See more keywords
Modulation of the magnetic dynamics of pentagonal-bipyramidal Co(II) complexes by fine-tuning the coordination microenvironment.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02345h
Abstract: Four air-stable mononuclear Co(II) complexes, with the formulas [Co(dapbh)(H2O)(CH3OH)] (1), [Co(Hdapbh)(N3)(CH3OH)]·(CH3OH) (2), [Co(H2aapbh)(CH3OH)2]·(NO3)2 (3) and [Co(H2bapbh)(H2O)(NO3)]·(NO3) (4), have been synthesized and structurally characterized by single crystal X-ray diffraction. In all of the complexes, the Co(II)… read more here.
Keywords: magnetic dynamics; dynamics pentagonal; pentagonal bipyramidal; ch3oh ... See more keywords