Sulfur Transfer Versus Phenyl Ring Transfer in the Gas Phase: Sequential Loss of CH3OH and CH3O–P=O from Protonated Phosphorothioates
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DOI: 10.1007/s13361-018-2098-4
Abstract: AbstractCollisional activation fragmentation of protonated phosphorothioates leads to skeletal rearrangement and formation of aryl sulfenylium cation (R-PhS+) via successive eliminations of CH3OH and CH3O–P=O. To better understand this unusual fragmentation reaction, isotope-labeling experiments and density… read more here.
Keywords: atom; ch3oh ch3o; phenyl ring; protonated phosphorothioates ... See more keywords