Facile Access to Completely Deuterated Single-Chain Nanoparticles Enabled by Intramolecular Azide Photodecomposition.
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecular rapid communications"
DOI: 10.1002/marc.201900046
Abstract: Access to completely deuterated single-chain nanoparticles (dSCNPs) has remained an unresolved issue. Herein, the first facile and efficient procedure to produce dSCNPs is reported, which comprises: i) the use of commercially available perdeuterated cyclic ether… read more here.
Keywords: completely deuterated; access completely; deuterated single; chain nanoparticles ... See more keywords
Tuning the Internal Compartmentation of Single-Chain Nanoparticles as Fluorescent Contrast Agents.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200618
Abstract: Controlling the internal structures of single-chain nanoparticles (SCNPs) is an important factor for their targeted chemical design and synthesis, especially in view of nanosized compartments presenting different local environments as a main feature to embed… read more here.
Keywords: contrast agents; chain nanoparticles; single chain; tuning internal ... See more keywords
CO2-Responsive Polymer Single-Chain Nanoparticles and Self-Assembly for Gas-Tunable Nanoreactors
Sign Up to like & getrecommendations! Published in 2017 at "Chemistry of Materials"
DOI: 10.1021/acs.chemmater.7b01656
Abstract: CO2-responsive polymer single-chain nanoparticles (SCNPs) and self-assembled micellar aggregates are investigated as gas-controlled, rate- and size-tunable nanoreactors of gold nanoparticles (AuNPs). On one hand, SCNPs are prepared from a random copolymer of poly{(N,N-dimethylaminoethyl methacrylate)-co-4-methyl-[7-(methacryloyl)oxy-ethyl-oxy]coumarin} (P(DMAEMA-co-CMA)).… read more here.
Keywords: chain; polymer single; responsive polymer; co2 responsive ... See more keywords
Disentangling Component Dynamics in an All-Polymer Nanocomposite Based on Single-Chain Nanoparticles by Quasielastic Neutron Scattering
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecules"
DOI: 10.1021/acs.macromol.1c02382
Abstract: We have investigated an all-polymer nanocomposite (NC) consisting of single-chain nanoparticles (SCNPs) immersed in a matrix of linear chains of their precursors (25/75% composition in weight). The SCNPs were previously synthesized via “click” chemistry, which… read more here.
Keywords: polymer nanocomposite; single chain; quasielastic neutron; neutron scattering ... See more keywords
Size of Elastic Single-Chain Nanoparticles in Solution and on Surfaces
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecules"
DOI: 10.1021/acs.macromol.7b01199
Abstract: We introduce herein a simple model of covalent-bonded single-chain nanoparticles (SCNPs) by considering these intrachain cross-linked nano-objects as elastic unimolecular networks. According to this model, each SCNP is regarded as a network of elastic strands… read more here.
Keywords: chain nanoparticles; size; solution; free energy ... See more keywords
Molecular Dynamics in Polystyrene Single-Chain Nanoparticles
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecules"
DOI: 10.1021/acs.macromol.9b02070
Abstract: The molecular dynamics of polystyrene (PS) single-chain nanoparticles (SCNPs) with variable molecular weights and irreversible intramolecular cross-linking densities was studied, by employing broadband dielectric spectroscopy, supplemented by calorimetry (differential scanning calorimetry, DSC), in the melt.… read more here.
Keywords: polystyrene single; dynamics polystyrene; molecular dynamics; chain nanoparticles ... See more keywords
100th Anniversary of Macromolecular Science Viewpoint: Re-examining Single-Chain Nanoparticles
Sign Up to like & getrecommendations! Published in 2020 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.0c00774
Abstract: Single-chain nanoparticles (SCNP) are a class of polymeric nanoparticles obtained from the intramolecular cross-linking of polymers bearing reactive pendant groups. The development of SCNP has draw... read more here.
Keywords: anniversary macromolecular; macromolecular science; chain nanoparticles; 100th anniversary ... See more keywords
Neat Protein Single-Chain Nanoparticles from Partially Denatured BSA
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c04805
Abstract: The main challenge for the preparation of protein single-chain nanoparticles (SCNPs) is the natural complexity of these macromolecules. Herein, we report the suitable conditions to produce “neat” bovine serum albumin (BSA) single-chain nanoparticles (SCNPs) from… read more here.
Keywords: protein single; chain nanoparticles; single chain; partially denatured ... See more keywords
Self-assembly and disassembly of stimuli responsive tadpole-like single chain nanoparticles using a switchable hydrophilic/hydrophobic boronic acid cross-linker
Sign Up to like & getrecommendations! Published in 2017 at "Polymer Chemistry"
DOI: 10.1039/c7py00828g
Abstract: Living systems are driven by molecular machines that are composed of folded polypeptide chains, which are assembled together to form multimeric complexes. Although replicating this type of system is a longstanding goal in polymer science,… read more here.
Keywords: chain; chain nanoparticles; assembly; cross linker ... See more keywords
M24+ paddlewheel clusters as junction points in single-chain nanoparticles
Sign Up to like & getrecommendations! Published in 2019 at "Polymer Chemistry"
DOI: 10.1039/c8py01486h
Abstract: A straightforward approach to incorporate copper and molybdenum dimetallic clusters into well-defined single-chain nanoparticles, featuring unique paddlewheel structures as junction points, is introduced. read more here.
Keywords: junction points; single chain; paddlewheel; chain nanoparticles ... See more keywords
A method to estimate the size of single-chain nanoparticles under severe crowding conditions
Sign Up to like & getrecommendations! Published in 2022 at "RSC Advances"
DOI: 10.1039/d1ra09088g
Abstract: Single-chain nanoparticles (SCNPs) result from the folding of isolated polymer chains via intramolecular interactions. Currently, there is no theory able to rationalize the astonishing conformational behaviour of SCNPs under severe crowding conditions (e.g., highly concentrated… read more here.
Keywords: severe crowding; single chain; chain nanoparticles; method estimate ... See more keywords