Articles with "chain orientation" as a keyword



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A molecular dynamics study of epitaxy-induced chain orientation and ordering of isotactic polypropylene

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Published in 2020 at "Polymer"

DOI: 10.1016/j.polymer.2020.122987

Abstract: Abstract Phase selective nucleation of single chain isotactic polypropylene (iPP) into specific crystalline polymorphs is enabled by heterogeneous nucleating agents. Molecular dynamics simulations were used to investigate the ordering of isolated iPP chains over ideal… read more here.

Keywords: chain; orientation; molecular dynamics; ipp ... See more keywords
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Effect of Chain Orientation and Stretch on the Stress Overshoot of Entangled Polymeric Materials under Start-Up Shear

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Published in 2017 at "Macromolecules"

DOI: 10.1021/acs.macromol.7b00288

Abstract: One of the most important nonlinear rheological phenomena in flowing polymeric materials is the stress overshoot under start-up shear at sufficiently high shear rates γ, i.e., γ > τd–1, where τd is the terminal relaxation… read more here.

Keywords: entangled polymeric; start shear; chain orientation; stress overshoot ... See more keywords