Well‐Defined Poly(HPMAm) Brushes via Surface‐Initiated RAFT Polymerization; A Mixed‐Chain Transfer Agent (CTA) Approach
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Materials Interfaces"
DOI: 10.1002/admi.202500196
Abstract: Over three decades, efforts to prevent non‐specific protein adsorption on surfaces have improved; however, developing well‐defined antifouling coatings remains a challenge in biomaterials research. In this study, a rapid and straightforward protocol relying on surface‐initiated… read more here.
Keywords: chain transfer; well defined; polymerization; poly hpmam ... See more keywords
Design of 2‐hydroxyethyl methacrylate‐functional macromonomer dispersants by semi‐batch cobalt chain transfer polymerization
Sign Up to like & getrecommendations! Published in 2019 at "AIChE Journal"
DOI: 10.1002/aic.16723
Abstract: Acrylic resins for automotive coatings are produced in nonaqueous dispersions (NAD) of nanometer size. These must be sterically stabilized by oligomeric dispersants, which are complex reactive oligomers possessing vinyl and hydroxyl functionalities, controlling the size… read more here.
Keywords: cobalt chain; chain transfer; batch; batch cobalt ... See more keywords
Synthesis of a water‐soluble chain transfer agent and its application in gel dispersions
Sign Up to like & getrecommendations! Published in 2024 at "Journal of Applied Polymer Science"
DOI: 10.1002/app.55205
Abstract: Pre‐crosslinked gel particles, colloidal dispersion gels, and polymer microspheres are often used as profile‐controlling and flooding agents to displace residual crude oil from formations. The preparation process of these profile‐controlling and flooding agents is complicated.… read more here.
Keywords: chain transfer; soluble chain; hydrogel dispersions; gel dispersions ... See more keywords
Neodymium‐Mediated Coordinative Chain Transfer Homopolymerization of Bio‐Based Myrcene and Copolymerization With Butadiene and Isoprene
Sign Up to like & getrecommendations! Published in 2024 at "Journal of Applied Polymer Science"
DOI: 10.1002/app.56557
Abstract: Coordinative chain transfer polymerization (CCTP) has emerged as a powerful strategy in controlling the polymerization behavior of petroleum‐based diene monomers of butadiene (BD) and isoprene (Ip) and has been extensively studied in the past few… read more here.
Keywords: chain transfer; coordinative chain; polymerization; butadiene isoprene ... See more keywords
Bifunctional Initiators as Tools to Track Chain Transfer during the CROP of 2-Oxazolines.
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecular rapid communications"
DOI: 10.1002/marc.201700396
Abstract: Detailed kinetic studies during the cationic ring-opening polymerization (CROP) of 2-ethyl-2-oxazoline (EtOx) are conducted using four bifunctional bromo-type initiators in N,N-dimethylformamide (DMF) at 140 °C. Serving as models to quantify chain transfer to monomer occurring… read more here.
Keywords: chain; molar mass; crop; chain transfer ... See more keywords
Peculiar Behaviour of Methyl Methacrylate (MMA) Emulsion Polymerization-induced Self-assembly (PISA) Mediated by RAFT Using Poly(methacrylic acid) (PMAA) Macromolecular Chain Transfer Agent.
Sign Up to like & getrecommendations! Published in 2024 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202400141
Abstract: Reversible addition-fragmentation chain transfer (RAFT) emulsion polymerization of methyl methacrylate (MMA) is successfully performed in water in the presence of a poly(methacrylic acid) (PMAA) macromolecular chain transfer agent (macroCTA) leading to the formation of self-stabilized… read more here.
Keywords: chain transfer; emulsion polymerization; mma; chain ... See more keywords
Nitriles as Functionalization and Coupling Agents for Polyolefins Obtained by Coordinative Chain Transfer Polymerization.
Sign Up to like & getrecommendations! Published in 2024 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202400226
Abstract: Coordinative chain transfer polymerization (CCTP) of ethylene and its copolymerization with 1,3-butadiene was conducted in toluene at 80 °C using a combination of {(Me2Si(C13H8)2)Nd(μ-BH4)[(μ-BH4)Li(THF)]}2 (1) metal complex and various organomagnesium compounds used as chain transfer… read more here.
Keywords: chain transfer; magnesium; polymerization; coordinative chain ... See more keywords
Precise Control of Molecular Weight Characteristics of Charge‐Shifting Poly(2‐(N,N‐Dimethylamino)Ethylacrylate) Synthesized by Reversible Addition‐Fragmentation Chain Transfer Polymerization
Sign Up to like & getrecommendations! Published in 2024 at "Macromolecular Rapid Communications"
DOI: 10.1002/marc.202400640
Abstract: Poly(2‐(N,N‐dimethylamino)ethyl acrylate) (PDMAEA) is a promising charge‐shifting polycation with the capacity to form a range of morphologically distinct polyelectrolyte assemblies. Nevertheless, the basic character of the monomer and its hydrolytic instability impedes its controlled synthesis… read more here.
Keywords: chain transfer; poly dimethylamino; polymerization; control ... See more keywords
Reversible addition–fragmentation chain transfer (co)polymerization of conjugated diene monomers: butadiene, isoprene and chloroprene
Sign Up to like & getrecommendations! Published in 2017 at "Polymer International"
DOI: 10.1002/pi.5173
Abstract: This review provides a critical survey of the literature on reversible addition–fragmentation chain transfer (RAFT) (co)polymerization of industrially significant conjugated diene monomers, specifically butadiene, isoprene and chloroprene. There is a focus on polymerizations performed in… read more here.
Keywords: fragmentation chain; polymerization; conjugated diene; addition fragmentation ... See more keywords
Effects of chain transfer agent on the electron beam-induced graft polymerization of glycidyl methacrylate in emulsion phase
Sign Up to like & getrecommendations! Published in 2017 at "Colloid and Polymer Science"
DOI: 10.1007/s00396-017-4088-7
Abstract: The graft polymerization of glycidyl methacrylate from irradiated polyethylene/polypropylene (PE/PP) in the presence of the chain transfer agent 4-cyano-4-((phenylcarbonothioyl)thio) pentanoic acid (CPPA) was studied at 40 °C using pre-irradiation grafting technique. Free radical active sites on… read more here.
Keywords: chain transfer; transfer agent; glycidyl; glycidyl methacrylate ... See more keywords
Reversible addition fragmentation chain transfer polymerization of styrene from the edge of graphene oxide nanolayers
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Polymer Research"
DOI: 10.1007/s10965-017-1193-8
Abstract: A graphene oxide modifier containing chain transfer agent moieties (CR) was synthesized by an esterification reaction between 1,4-butanediol and 2-(dodecylthiocarbonothioylthio)-2-methylpropionic acid. CR moieties were grafted at the edge of GO in low and high graft… read more here.
Keywords: graphene oxide; spectroscopy; chain transfer;