Highly Thermally Stable, Reversible and Flexible Main Chain-Type Benzoxazine Hybrid Incorporating Both Polydimethylsiloxane and Double-Decker-Shaped Polyhedral Silsesquioxane Units through Diels-Alder Reaction.
Sign Up to like & getrecommendations! Published in 2023 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200910
Abstract: We synthesized a new bifunctional furan derivative (PDMS-FBZ) through a sequence of hydrosilylation of nadic anhydride (ND) with polydimethylsiloxane (PDMS), reaction of the product with p-aminophenol to form PDMS-ND-OH, and its subsequent Mannich reaction with… read more here.
Keywords: reaction; main chain; chain type; diels alder ... See more keywords
Poly(aryl ether nitrile)s containing flexible side-chain-type quaternary phosphonium cations as anion exchange membranes
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DOI: 10.1007/s40843-019-1222-x
Abstract: In order to effectively improve the properties of anion exchange membrane (AEM) materials, a series of novel poly(aryl ether nitrile)s with flexible side-chain-type quaternary phosphonium cations (PAEN-TPP- x ) were designed and prepared on the… read more here.
Keywords: chain type; flexible side; quaternary phosphonium; side chain ... See more keywords
Side-Chain-Type Metallo-Macrocycles: η5-Cyclopentadienylcobalt-η4-cyclobutadiene-Incorporated Conjugated Macrocycle.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c03286
Abstract: This work reports the synthesis of a 1,3-linked tetracyclopentadienylcobalt-cyclobutadiene macrocycle ([CpCoCb]4) via Pt-templated cyclization. Structural characterization by SCXRD confirms a Ci-symmetric nanohoop (1.5 nm diameter). Unique CH-π interactions drive the 1D channel packing. Electrochemical studies… read more here.
Keywords: macrocycle; chain type; macrocycles cyclopentadienylcobalt; type metallo ... See more keywords