Methyl Scanning for Mechanochemical Chalcogen‐Bonding Cascade Switches
Sign Up to like & getrecommendations! Published in 2020 at "ChemistryOpen"
DOI: 10.1002/open.201900288
Abstract: Abstract Chalcogen‐bonding cascade switching was introduced recently to produce the chemistry tools needed to image physical forces in biological systems. In the original flipper probe, one methyl group appeared to possibly interfere with the cascade… read more here.
Keywords: bonding cascade; chalcogen bonding; methyl group;
Chalcogen bonding in materials chemistry
Sign Up to like & getrecommendations! Published in 2020 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2020.213464
Abstract: Abstract This review examines recent literature in search for evidence of the influence that chalcogen bonding has on the structure and properties of functional materials. Key examples from research on charge transfer salts, neutral heterocyclic… read more here.
Keywords: materials chemistry; bonding materials; chemistry; chalcogen bonding ... See more keywords
Supramolecular bimetallic vanadium(V) complex driven by hydrogen bonding and O∙∙∙O chalcogen bonding interaction: Oxidation of cyclohexane and its application toward C H bond activation
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119837
Abstract: Abstract Vanadium(V) complex was synthesized in good yield and characterized by FT-IR, UV–Visible and NMR spectroscopy. The structure of the complex was confirmed by single X-ray crystallography. X-ray structural analysis the complex featuring O∙∙∙O chalcogen… read more here.
Keywords: bonding interaction; vanadium complex; chalcogen bonding; interaction ... See more keywords
The S ⋅⋅⋅ Hal and Se ⋅⋅⋅ Hal chalcogen bonding in a series of thiourea, selenourea and their derivatives
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Solid State Chemistry"
DOI: 10.1016/j.jssc.2020.121759
Abstract: Abstract The chalcogen bonding (ChB) in a series of thiourea, selenourea and their derivatives has been investigated in the present paper. Thus, selenourea and dimethylselenourea undergo dimerization and trimerization processes in the presence of various… read more here.
Keywords: chalcogen bonding; series thiourea; selenourea derivatives; chalcogen ... See more keywords
Iso-Tellurazolium-N-Phenoxides: A Family of Te···O Chalcogen-Bonding Supramolecular Building Blocks.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02585
Abstract: Formal substitution of the oxygen atom of an iso-tellurazole N-oxide with deprotonated (ortho, meta, and para)-hydroxyphenyl groups generated molecules that readily aggregate through Te···O chalcogen bonding (ChB) interactions. The molecules undergo autoassociation in solution, as… read more here.
Keywords: family chalcogen; iso tellurazolium; chalcogen bonding; iso tellurazole ... See more keywords
Solution Self-Assembly of Chalcogen-Bonding Polymer Partners
Sign Up to like & getrecommendations! Published in 2020 at "ACS Macro Letters"
DOI: 10.1021/acsmacrolett.0c00511
Abstract: Chalcogen bonding is regarded as a form of noncovalent interaction; however, harnessing chalcogen bonds to drive macromolecular self-assembly remains unexplored. Here we report two classes of chalc... read more here.
Keywords: self assembly; chalcogen bonding; assembly chalcogen; polymer partners ... See more keywords
Chalcogen Bonding and Hydrophobic Effects Force Molecules into Small Spaces.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.0c01290
Abstract: Supramolecular capsules are desirable containers for the study of molecular behavior in small spaces, and offer applications in transport, catalysis and material science. We report here the use of chalcogen bonding to form container assemblies… read more here.
Keywords: chalcogen bonding; cyclohexane carboxylic; capsule; small spaces ... See more keywords
Redox-Switchable Chalcogen Bonding for Anion Recognition and Sensing
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c02924
Abstract: Inspired by the success of its related sigma-hole congener halogen bonding (XB), chalcogen bonding (ChB) is emerging as a powerful noncovalent interaction with a plethora of applications in supramolecular chemistry and beyond. Despite its increasing… read more here.
Keywords: chb; anion recognition; chalcogen bonding; redox ... See more keywords
Multistate Redox-Switchable Ion Transport Using Chalcogen-Bonding Anionophores
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c12892
Abstract: Synthetic supramolecular transmembrane anionophores have emerged as promising anticancer chemotherapeutics. However, key to their targeted application is achieving spatiotemporally controlled activity. Herein, we report a series of chalcogen-bonding diaryl tellurium-based transporters in which their anion… read more here.
Keywords: chalcogen bonding; redox; multistate redox; transport ... See more keywords
Reversible Self-Assembly of Supramolecular Vesicles and Nanofibers Driven by Chalcogen-Bonding Interactions.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b04569
Abstract: Chalcogen-bonding interactions have been viewed as new non-covalent forces in supramolecular chemistry. However, harnessing chalcogen bonds to drive molecular self-assembly processes is still unexplored. Here we report for the first time a novel class of… read more here.
Keywords: self assembly; chalcogen bonding; chalcogen; assembly supramolecular ... See more keywords
Thienoisoindigo-Based Semiconductor Nanowires Assembled with 2-Bromobenzaldehyde via Both Halogen and Chalcogen Bonding
Sign Up to like & getrecommendations! Published in 2018 at "Scientific Reports"
DOI: 10.1038/s41598-018-32486-z
Abstract: We fabricated nanowires of a conjugated oligomer and applied them to organic field-effect transistors (OFETs). The supramolecular assemblies of a thienoisoindigo-based small molecular organic semiconductor (TIIG-Bz) were prepared by co-precipitation with 2-bromobenzaldehyde (2-BBA) via a… read more here.
Keywords: chalcogen bonding; thienoisoindigo based; tiig; semiconductor ... See more keywords