Redox Activity of Electronically Excited Phosphorus-Corroles with Axial Chalcogenation.
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DOI: 10.1002/cplu.202500137
Abstract: Quest for visible-light absorbing metal-free corroles is of increased research interest for both electrocatalytic and photocatalytic applications among others. To this direction, phosphorus corrole (PC) and its functional derivatives hold great potential. In this study,… read more here.
Keywords: equation; redox; equation equation; chalcogenation ... See more keywords
7-Azabicyclo[2.2.1]heptadienes in electrophilic chalcogenation reactions
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DOI: 10.1007/s11172-017-1765-0
Abstract: Reactions of electrophilic chalcogenation (sulfenylation and selenenylation) of 7-azabicyclo[2.2.1]heptadiene derivatives with electron-withdrawing substituents at the nitrogen atom and the double bond were found to proceed trans-stereospecifically with the formation of 1,2-addition products, resulting from the… read more here.
Keywords: electrophilic chalcogenation; azabicyclo heptadienes; chalcogenation reactions; heptadienes electrophilic ... See more keywords
Copper-Catalyzed Regioselective Remote C-H Bond Chalcogenation of Aromatic Amine Derivatives without Using Any Large Template.
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DOI: 10.1021/acs.orglett.2c04261
Abstract: A mild and convenient strategy has been developed for the para-selective chalcogenation of anilide scaffolds via C-H bond functionalization. This methodology employs one of the most earth-abundant and inexpensive Cu(II) catalysts and a commercially available… read more here.
Keywords: regioselective remote; methodology; chalcogenation; catalyzed regioselective ... See more keywords
Copper(II)-Catalyzed Direct C3 Chalcogenylation of Indoles
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DOI: 10.3390/molecules30091870
Abstract: 3-Chalcogenylindoles serve as crucial building blocks in organic synthesis and pharmaceutical chemistry. Herein, we describe a simple and general synthesis of 3-chalcogenylindoles through the direct C–H chalcogenation of indoles using N-selenophthalimide and N-sulfenylsuccinimide as chalcogenation… read more here.
Keywords: chemistry; catalyzed direct; direct chalcogenylation; chalcogenylation indoles ... See more keywords