A non-centrosymmetric chalcohalide synthesized through the combination of chemical tailoring with aliovalent substitution.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc07084g
Abstract: A new non-centrosymmetric (NCS) chalcohalide, [Sr4Cl2][Ge3S9], was successfully designed and synthesized through combining chemical tailoring with aliovalent substitution strategies from the maternal [NaSr4Cl][Ge3S10]. It can exhibit a large SHG effect (0.97 × AgGaS2), a wide… read more here.
Keywords: non centrosymmetric; chalcohalide; chemical tailoring; tailoring aliovalent ... See more keywords
Pb3SBrI3: the first Pb-based chalcohalide with multiple halogens features a unique two-dimensional structure composed of diverse Pb-centered polyhedra.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02038f
Abstract: Chalcohalides are attractive multifunctional candidates for new material due to their diverse crystal structures and the characteristics that come from the fusing of chalcogenides and halides. Here, we successfully synthesized a new Pb-based chalcohalide with… read more here.
Keywords: structure; chalcohalide; chalcohalide multiple; based chalcohalide ... See more keywords