Syntheses and characterization of hepta-coordinated Group 4 amidinate complexes.
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DOI: 10.1039/c8dt02523a
Abstract: Tri-amidinate chloride complexes M[MeC(NiPr)2]3Cl [M = Zr (1), Hf (2)] have been prepared from MCl4 and lithium amidinate Li[MeC(NiPr)2]. The uncommon hepta-coordinated complexes Zr-Cl (1) and Hf-Cl (2) undergo metathesis reactions with 1 equiv. of… read more here.
Keywords: amidinate; syntheses characterization; hepta coordinated; characterization hepta ... See more keywords