Synthesis, characterization and X-ray crystal structure of Tp*WII{(R)-(+)-NHCH(Me)Ph}(CO)2
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.120016
Abstract: Abstract Reaction of Tp*WIII(CO)2 [Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate] with (R)-(+)-α-methylbenzylamine [(R)-(+)-LH2] in dichloromethane yields blue, diamagnetic Tp*WII{(R)-(+)-LH}(CO)2, which has been characterised by microanalysis, mass spectrometry, infrared, 1H NMR, 13C{1H} NMR and electronic spectroscopies, and X-ray crystallography.… read more here.
Keywords: wii; synthesis characterization; characterization ray; crystal structure ... See more keywords
Synthesis, characterization, X-ray crystallography and stability in aqueous medium of trans -[Ru(CO)(NH 3 ) 4 P(OH) 3 ] 2+
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DOI: 10.1016/j.poly.2016.12.019
Abstract: Abstract Here, we report the synthesis, characterization, crystal data and DFT calculation of a new water-soluble ruthenium(II) carbonyl complex. The trans-[Ru(CO)(NH3)4P(O)(OH)2]Cl is a robust complex in aqueous media. The pKa of 3.3 for the phosphorous… read more here.
Keywords: trans nh3; crystallography stability; characterization ray; ray crystallography ... See more keywords