Synthesis, characterization, and reactivity of copper complexes supported by the TPMEN ligand framework
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.09.041
Abstract: Abstract Two new Cu(II) complexes supported by nitrogen-rich ligands have been synthesized and characterized by absorption spectroscopy, magnetic moment, and cyclic voltammetry. Complex 1 is supported by the ligand TPMEN (N,N,N′-tris(2-pyridylmethyl)-N′-methylethylenediamine) with two amine and… read more here.
Keywords: reactivity copper; complexes supported; copper complexes; characterization reactivity ... See more keywords
Synthesis, spectral characterization, reactivity and DFT studies of novel ligand phenylseleno benzylacetate (L) and its complexes with group 12 metal chlorides
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2018.05.091
Abstract: Abstract C6H5Se-Na+ (generated in-situ by NaBH4 reduction of (C6H5Se)2) on reaction with bromo benzylacetate under N2 atmosphere results in the formation of phenylseleno benzylacetate (L) as viscous oil. Its complexes having the formula [ZnCl2(L)] (1),… read more here.
Keywords: phenylseleno benzylacetate; benzylacetate; synthesis spectral; characterization reactivity ... See more keywords
Synthesis, Characterization, and Reactivity of an Ethynyl Benziodoxolone (EBX)-Acetonitrile Complex.
Sign Up to like & getrecommendations! Published in 2019 at "Organic letters"
DOI: 10.1021/acs.orglett.9b00005
Abstract: The synthesis of a crystalline ethynyl-1,2-benziodoxol-3(1 H)-one (EBX)-acetonitrile complex is described. EBX has been widely used as an active species for a variety of reactions; however, its high instability has so far prevented its isolation.… read more here.
Keywords: ebx acetonitrile; characterization reactivity; synthesis characterization; acetonitrile complex ... See more keywords
A germanimidoyl chloride: synthesis, characterization and reactivity.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d2cc05970c
Abstract: The first germanimidoyl chloride MsFluindtBu-Ge(Cl)NMes (2, where MsFluindtBu is a bulky hydrindacene skeleton) was synthesized through the reaction of MsFluindtBu-GeCl (1) and mesityl azide (MesN3). In contrast, treatment of 1 with a less bulky azide… read more here.
Keywords: germanimidoyl chloride; msfluindtbu; characterization reactivity; synthesis characterization ... See more keywords
Synthesis, characterization, and reactivity of [Pd(phosphine)(py)Cl2] (PEPPSI) and [Pd(phosphine)Cl2]2 complexes.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00293d
Abstract: The synthesis of novel phosphine palladium PEPPSI and dimer complexes bearing RuPhos, SPhos and XPhos phosphines is reported. The crystal structures of XPhos Pd PEPPSI with pyridine, SPhos Pd PEPPSI with 3-chloropyridine as throw-away ligands… read more here.
Keywords: phosphine; phosphine cl2; characterization reactivity; peppsi ... See more keywords
Spectroscopic characterization and reactivity of a high valent (L)Cu(III) species supported by proline-based pseudo peptide
Sign Up to like & getrecommendations! Published in 2023 at "Dalton Transactions"
DOI: 10.1039/d3dt00697b
Abstract: Inspired by copper-based metalloenzymes, we aim to incorporate amino acids into our ligands to facilitate active copper intermediates that serve as functional and structural models for these enzymes. Herein, we report the synthesis of a… read more here.
Keywords: reactivity high; proline based; characterization reactivity; high valent ... See more keywords