Solid-state and solution-phase characterization of SmII-aza[2.2.2]cryptate and its methylated analogue.
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DOI: 10.1039/d2dt01823c
Abstract: Two new SmII-azacryptates are reported that differ in steric hindrance and Lewis basicity of donor atoms. The sterically hindered complex has a smaller coordination number and a more negative electrochemical potential than the complex with… read more here.
Keywords: characterization smii; state solution; solution phase; solid state ... See more keywords