Photochemical Generation and Characterization of Di-tert-butylsilylene (SitBu2) in Solution
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DOI: 10.1021/acs.organomet.8b00902
Abstract: Di-tert-butylsilylene (SitBu2) has been detected directly in solution and its reactivity characterized by laser flash photolysis methods. Laser photolysis of 7,7-di-tert-butyl-7-silabicyclo[4.1.0]heptane (5) affords a transient product that exhibits λmax ≈ 520 nm and decays on… read more here.
Keywords: photochemical generation; butylsilylene sitbu2; tert butylsilylene; characterization tert ... See more keywords