Solvent-assisted synthesis of a shape-persistent chiral polyaza gigantocycle characterized by a very large internal cavity and extraordinarily high amplitude of the ECD exciton couplet.
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DOI: 10.1039/c8cc10184a
Abstract: A giant, chiral square-shaped octaimine macrocycle has been obtained in a controlled manner from readily available and inexpensive substrates: 9,10-diphenylanthracene-based dialdehyde and trans-1,2-diaminocyclohexane. Reduction of the polyimine led to a chiral octaamine characterized by a… read more here.
Keywords: characterized large; solvent assisted; cavity; assisted synthesis ... See more keywords