Transforming benzylideneamine N,C-chelate boron compounds to BN-cycloocta-/cyclohepta-trienes bearing a tetrasubstituted B[double bond, length as m-dash]N unit via photoisomerization.
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DOI: 10.1039/c8cc04535f
Abstract: A series of benzylideneamine N,C-chelate boron compounds have been found to undergo rapid multistructural transformations with UV irradiation, yielding new BN-cycloocta-1,3,6-triene ((4Z,6Z)-1,2,3,8-tetrahydro-1,2-azaborocine) and BN-cyclohepta-1,3,5-triene (2,7-dihydro-1H-1,2-azaborepine) derivatives with a tetrasubstituted B[double bond, length as m-dash]N unit… read more here.
Keywords: boron compounds; benzylideneamine chelate; tetrasubstituted double; bond length ... See more keywords