Estimation of non-covalent CH⋯π, π⋯π (chelate ring) and hydrogen bonding interactions in vanadium(V) Schiff base complexes: Methylene spacer regulated variation in self-assembly
Sign Up to like & getrecommendations! Published in 2017 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.07.056
Abstract: Abstract Two structurally similar mononuclear vanadium(V) complexes, [VO 2 (L 1 )] ( 1 ) and [VO 2 (L 2 )] ( 2 ) [where HL 1 = 1-(2-(dimethylamino)ethyliminomethyl)naphthalen-2-ol and HL 2 = 1-(2-(diethylamino)ethyliminomethyl)naphthalen-2-ol] have been synthesized… read more here.
Keywords: non covalent; ring hydrogen; chelate ring; covalent chelate ... See more keywords
One-pot synthesis of a PCsp3P-type pincer complex via double C H palladation of a large chelate ring
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2020.114415
Abstract: Abstract The diphosphine proligand R2P(CH2)5PR2 (R = i-Pr) reacts with PdCl2 or Pd(PhCN)2Cl2 in CH2Cl2 to give the 2:2 adduct trans-{µ-kP,kP′-R2P(CH2)5PR2}2Pd2Cl4 (1) featuring a 16-atom chelate ring, along with other uncharacterized species. Treating 1 with AgOTf or… read more here.
Keywords: type pincer; chelate ring; pcsp3p type; one pot ... See more keywords
Highly Selective Aluminum(III) Ion Sensing with Luminescent Iridium(III) Complexes Bearing a Distorted 2,2'-Bipyridine-3,3'-diol Moiety Utilizing a Rigidified Seven-Membered Chelate Ring.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b00373
Abstract: To create an ion sensor utilizing a rigidified seven-membered chelate ring, we developed two Ir(III) complexes with 2,2'-bipyridine-3,3'-diol (bpy(OH)2, bpydL) ligands as reaction centers, namely Ir1 ([Ir(ppy)2{bpy(O-)(OH)}], ppy = 2-phenylpyridine) and Ir2 ([Ir(bzq)2{bpy(O-)(OH)}], bzq =… read more here.
Keywords: iii; chelate ring; membered chelate; seven membered ... See more keywords
Influence of Substituents in a Six-Membered Chelate Ring of HG-Type Complexes Containing an N→Ru Bond on Their Stability and Catalytic Activity
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28031188
Abstract: An efficient approach to the synthesis of olefin metathesis HG-type catalysts containing an N→Ru bond in a six-membered chelate ring was proposed. For the most part, these ruthenium chelates can be prepared easily and in… read more here.
Keywords: catalytic activity; containing bond; chelate; chelate ring ... See more keywords