Tuning the O2 Binding Affinity of Cobalt(II) Centers by Changing the Structural and Electronic Properties of the Distal Substituents on Azole-Based Chelating Ligands.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b02241
Abstract: The effects of the substituents on the chelating ligands located in the secondary coordination sphere on the O2 affinity of cobalt(II) centers have been explored. The combination of facially capping tridentate tris(pyrazolyl)borates (= TpMe2,4R) and… read more here.
Keywords: cobalt centers; cobalt center; cobalt; chelating ligands ... See more keywords
Manipulating clusters by regulating N,O chelating ligands: structures and multistep assembly mechanisms
Sign Up to like & getrecommendations! Published in 2020 at "CrystEngComm"
DOI: 10.1039/c9ce01730e
Abstract: We obtained a binuclear Gd(III) complex [Gd2(L1)2(NO3)4] (1, HL1 = (E)-2-(2-(pyridin-2-ylmethyleneamino)ethoxy)ethanol) by reacting N2O2-tetradentate chelating ligand HL1 with Gd(NO3)3·6H2O at solvothermal temperature of 100 °C. Time-dependent high-resolution electrospray ionization mass spectrometry (HRESI-MS) followed the formation… read more here.
Keywords: gd2; chelating ligands; manipulating clusters; clusters regulating ... See more keywords
A Brief Overview of the Microstructural Engineering of Inorganic–Organic Composite Membranes Derived from Organic Chelating Ligands
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DOI: 10.3390/membranes13040390
Abstract: This review presents a concise conceptual overview of membranes derived from organic chelating ligands as studied in several works. The authors’ approach is from the viewpoint of the classification of membranes by matrix composition. The… read more here.
Keywords: derived organic; microstructural engineering; organic chelating; membranes derived ... See more keywords
Thiourea-Derived Chelating Ligands and Their Organometallic Compounds: Investigations into Their Anticancer Activity
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DOI: 10.3390/molecules25163661
Abstract: Thiones have been investigated as ligands in metal complexes with catalytic and biological activity. We report the synthesis, characterization, and biological evaluation of a series of MII/III complexes of the general formulae [MII(cym)(L)Cl]X (cym =… read more here.
Keywords: organometallic compounds; chelating ligands; activity; derived chelating ... See more keywords