Chemical braking exhibited by ethynylhelicene (M)-nonamer in solution: Competitive reaction system of self-catalysis to form double-helix and approach towards equilibrium to form random-coil
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DOI: 10.1016/j.tet.2017.03.083
Abstract: Abstract Chemical braking occurs in a dilute solution during a structural change of ethynylhelicene (M)-nonamer from the metastable double-helix state to the random-coil state, being at equilibrium, where the reaction is initially rapid and then… read more here.
Keywords: chemical braking; double helix; random coil; form ... See more keywords