Insights into Chemically Fueled Supramolecular Polymers.
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DOI: 10.1021/acs.chemrev.1c00958
Abstract: Supramolecular polymerization can be controlled in space and time by chemical fuels. A nonassembled monomer is activated by the fuel and subsequently self-assembles into a polymer. Deactivation of the molecule either in solution or inside… read more here.
Keywords: deactivation; insights chemically; fueled supramolecular; activation deactivation ... See more keywords
Chemically Fueled Self-Sorted Hydrogels.
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DOI: 10.1021/jacs.1c10282
Abstract: Narcissistic self-sorting in supramolecular assemblies can help to construct materials with more complex hierarchies. Whereas controlled changes in pH or temperature have been used to this extent for two-component self-sorted gels, here we show that… read more here.
Keywords: chemically fueled; self sorted; sorted hydrogels; fueled self ... See more keywords
Chemically Fueled Reinforcement of Polymer Hydrogels.
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DOI: 10.1021/jacs.3c00668
Abstract: Carbodiimide-fueled anhydride bond formation has been used to enhance the mechanical properties of permanently crosslinked polymer networks, giving materials that exhibit transitions from soft gels to covalently reinforced gels, eventually returning to the original soft… read more here.
Keywords: carbodiimide; polymer hydrogels; mechanical properties; chemically fueled ... See more keywords
Morphological transitions in chemically fueled self-assembly.
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DOI: 10.1039/d1nr04954b
Abstract: In chemically fueled self-assembly, a reaction cycle activates and deactivates molecules for self-assembly. The resulting assembly is dynamic and should be endowed with unique behavior in this kinetically controlled regime. Recent works have mainly focused… read more here.
Keywords: fueled self; self assembly; transitions chemically; morphological transitions ... See more keywords
A chemically fueled supramolecular glue for self-healing gels
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DOI: 10.1039/d2sc03691f
Abstract: Chemically fueled supramolecular materials offer unique properties that include spatial and temporal control and even the ability to self-heal. Indeed, a few studies have demonstrated the ability to self-heal, however, the underlying mechanisms remain unclear.… read more here.
Keywords: fueled supramolecular; self healing; glue; self heal ... See more keywords