Articles with "chemisorption" as a keyword



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CO2 chemisorption behaviour of coordination-derived phenolate sorbents.

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Published in 2021 at "ChemSusChem"

DOI: 10.1002/cssc.202100666

Abstract: CO 2 chemisorption via C-O bond formation is an efficient methodology in carbon capture especially using phenolate-based ionic liquids (ILs) as the sorbents to afford carbonate products. However, most of the current IL systems involved… read more here.

Keywords: coordination; co2 chemisorption; behaviour coordination; chemisorption ... See more keywords
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Chemisorption of air CO2 on cellulose: an overlooked feature of the cellulose/NaOH(aq) dissolution system

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Published in 2017 at "Cellulose"

DOI: 10.1007/s10570-017-1288-8

Abstract: A natural abundance of the air CO2 in NaOH(aq) at low temperature was investigated in terms of cellulose-CO2 interactions upon cellulose dissolution in this system. An organic superbase, namely 1,8-diazabicyclo[5.4.0]undec-7-ene, DBU, known for its ability… read more here.

Keywords: system; cellulose; air co2; dissolution ... See more keywords
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High and efficient carbon dioxide chemisorption on a new high lithium-content ceramic; hexalithium cobaltate (Li6CoO4)

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Published in 2020 at "Chemical Engineering Journal"

DOI: 10.1016/j.cej.2019.123291

Abstract: Abstract Hexalithium cobaltate (Li6CoO4) was synthesized, characterized and tested as a possible carbon dioxide (CO2) captor. Li6CoO4 was prepared by solid-state reaction, where an initial structural analysis suggests high lithium ion diffusion, based on the… read more here.

Keywords: cobaltate li6coo4; co2; carbon dioxide; hexalithium cobaltate ... See more keywords
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High chemisorption abilities of hydrogen and oxygen on ultrasmall iron clusters: A first-principles study

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Published in 2018 at "Chemical Physics Letters"

DOI: 10.1016/j.cplett.2018.05.045

Abstract: Abstract The interactions between atoms and small metal clusters are of great significance in the exploration of novel bonding mechanism. We present the strong chemisorption abilities of ultrasmall iron clusters interacting with large numbers of… read more here.

Keywords: hydrogen oxygen; ultrasmall iron; chemisorption abilities; iron clusters ... See more keywords
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Experimental identification and thermodynamic analysis of ammonia sorption equilibrium characteristics on halide salts

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Published in 2018 at "Energy"

DOI: 10.1016/j.energy.2018.07.129

Abstract: Solid–gas chemisorption based on metal ammine complexes is a kind of promising energy-saving and environment-friendly technology for various thermal engineering applications such as chemical heat pump, thermochemical energy storage, chemisorption refrigeration, etc. The accurate thermodynamic… read more here.

Keywords: methodology; ammonia sorption; halide salts; equilibrium ... See more keywords
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Chemisorption and physisorption of fine particulate matters on the floating beads during Zhundong coal combustion

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Published in 2020 at "Fuel Processing Technology"

DOI: 10.1016/j.fuproc.2019.106310

Abstract: Abstract Floating beads rich in silica-aluminum oxide are hollow glass microspheres that can be obtained from fly ash by flotation. Floating beads have the advantages of high yield, low cost and easy access in the… read more here.

Keywords: floating beads; physisorption; chemisorption; coal combustion ... See more keywords
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Maleic acid modified cellulose for scavenging lead from water.

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Published in 2019 at "International journal of biological macromolecules"

DOI: 10.1016/j.ijbiomac.2019.02.037

Abstract: Macro, micro and nano fibrillary cellulose with sodium maleate groups was synthesized by the reaction of cellulose with maleic anhydride followed by sodium exchange of protons. In the present work, we demonstrate that these carboxylic… read more here.

Keywords: maleic acid; modified cellulose; water; ion ... See more keywords
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Chemisorption of microcystins to a thiol and amine functionalized organosilica

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Published in 2018 at "Separation and Purification Technology"

DOI: 10.1016/j.seppur.2018.01.004

Abstract: Abstract Microcystins are cyclic heptapeptide toxins produced by cyanobacteria that are frequently detected in surface waters during seasonal blooms. Chemisorption of microcystin through covalent bond formation to the acryloyl group common to all congeners was… read more here.

Keywords: thiol; adsorption; thiol amine; addition reaction ... See more keywords
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Stabilizing Single-Atom and Small-Domain Platinum via Combining Organometallic Chemisorption and Atomic Layer Deposition

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Published in 2017 at "Organometallics"

DOI: 10.1021/acs.organomet.6b00869

Abstract: Oxide-supported single-atom Pt materials are prepared by combining surface organometallic chemisorption with atomic layer deposition (ALD). Here Pt is supported as a discrete monatomic “pincer” complex, stabilized by an atomic layer deposition (ALD) derived oxide… read more here.

Keywords: stabilizing single; atomic layer; layer deposition; single atom ... See more keywords
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Tuning the Catalytic Activity of PdxNiy (x + y = 6) Bimetallic Clusters for Hydrogen Dissociative Chemisorption and Desorption

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Published in 2019 at "ACS Omega"

DOI: 10.1021/acsomega.9b01360

Abstract: Density functional theory was used to study dissociative chemisorption and desorption on PdxNiy (x + y = 6) bimetallic clusters. The H2 dissociative chemisorption energies and the H desorption energies at full H saturation were… read more here.

Keywords: dissociative chemisorption; bimetallic clusters; chemisorption desorption; chemisorption ... See more keywords

Defect engineered SnO2 nanoparticles enable strong CO2 chemisorption toward efficient electroconversion to formate.

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Published in 2022 at "Dalton transactions"

DOI: 10.1039/d1dt04045f

Abstract: Oxygen vacancy (Ov) engineering of SnO2 electrocatalysts plays a crucial role in realizing efficient CO2 electroreduction (CO2RR) into formate. Herein, we demonstrate the rational synthesis of highly dispersed SnO2 nanoparticle electrocatalysts with an ultrahigh Ov… read more here.

Keywords: electroconversion formate; chemisorption; formate; co2 ... See more keywords