Reversible Redox Chemistry of Anionic Imidazole-2-thione-Fused 1,4-Dihydro-1,4-diphosphinines
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DOI: 10.1021/acs.inorgchem.1c03620
Abstract: Anionic 1,4-dihydro-1,4-diphosphinines were synthesized from tricyclic 1,4-diphosphinines and isolated as blue powdery salts M[2a–2c]. Reaction of solutions of these monoanions with iodomethane led to P-methylated compounds 3a–3c. An oxidation/reduction cycle was examined, starting from solutions… read more here.
Keywords: anionic imidazole; chemistry anionic; chemistry; reversible redox ... See more keywords
Redox chemistry of an anionic dithiolene radical.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c8dt04989k
Abstract: The redox chemistry of the first stable anionic dithiolene radical 1˙ was investigated by both reactivity and cyclic voltammetry studies. While one-electron reduction of 1˙ by Cp2Co or KC8 affords the corresponding dithiolate dimers 2… read more here.
Keywords: chemistry anionic; redox chemistry; chemistry; dithiolene ... See more keywords