Nonaqueous Chemistry of Group 4 Oxo Clusters and Colloidal Metal Oxide Nanocrystals.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.1c01008
Abstract: We review the nonaqueous precursor chemistry of the group 4 metals to gain insight into the formation of their oxo clusters and colloidal oxide nanocrystals. We first describe the properties and structures of titanium, zirconium,… read more here.
Keywords: oxo clusters; oxide nanocrystals; clusters colloidal; chemistry ... See more keywords
Chemistry of group 5 metallaboranes with heterocyclic thiol ligands: a combined experimental and theoretical study.
Sign Up to like & getrecommendations! Published in 2021 at "Dalton transactions"
DOI: 10.1039/d0dt04362a
Abstract: Thermolysis of [(Cp*Nb)2(B2H6)2], 1b (Cp* = η5-C5Me5), with 2-mercaptobenzothiazole, C6H4NSCSH (MBT), and 2-mercaptobenzoxazole, C6H4NOCSH (MBO), yielded hydrogen substituted compounds 2 and 3 with a general formula [(Cp*Nb)2(B2H6)(B2H5L)] (2: L = C6H4NSCS and 3: L =… read more here.
Keywords: metallaboranes heterocyclic; c6h4nscs; chemistry; group metallaboranes ... See more keywords