Sustainable one-pot chemo-enzymatic synthesis of chiral furan amino acid from biomass via magnetic solid acid and threonine aldolase.
Sign Up to like & getrecommendations! Published in 2021 at "Bioresource technology"
DOI: 10.1016/j.biortech.2021.125344
Abstract: Sustainable synthesis of valuable noncanonical amino acids from renewable feedstocks is of great importance. Here, a feasible chemo-enzymatic procedure was developed for the synthesis of chiral β-(2-furyl)serine from biomass catalyzed by a solid acid catalyst… read more here.
Keywords: solid acid; amino; chemo enzymatic; biomass ... See more keywords
Chemo-Enzymatic Modification of the 5' Cap To Study mRNAs.
Sign Up to like & getrecommendations! Published in 2022 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00059
Abstract: ConspectusThe central dogma of molecular biology hinges on messenger RNA (mRNA), which presents a blueprint of the genetic information encoded in the DNA and serves as a template for translation into proteins. In addition to… read more here.
Keywords: modification; modification cap; cap; study ... See more keywords
Chemo-enzymatic Conversion of Glucose in 5-Hydroxymethylfurfural: The Joint Effect of Ionic Liquids and Ultrasound
Sign Up to like & getrecommendations! Published in 2020 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.0c02555
Abstract: For the valorization of lignocellulosic biomass, a key step is unlocking the conversion of glucose to suitable chemical platforms. To this aim, we herein describe the sequential chemo-enzymatic conversion of glucose into 5-hydroxymethylfurfural (5-HMF), in… read more here.
Keywords: chemo enzymatic; enzymatic conversion; conversion glucose; conversion ... See more keywords
Chemo-Enzymatic Synthesis and Characterization of Renewable Thermoplastic and Thermoset Isocyanate-Free Poly(hydroxy)urethanes from Ferulic Acid Derivatives
Sign Up to like & getrecommendations! Published in 2017 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.6b02022
Abstract: This study presents the syntheses and characterization of renewable nonisocyanate polyurethanes (NIPUs) from a new family of aromatic C5-cyclocarbonate precursors with different functionalities obtained from nontoxic ferulic acid derivatives by glycidylation and carbonation under high… read more here.
Keywords: characterization renewable; chemo enzymatic; enzymatic synthesis; ferulic acid ... See more keywords
Chemo-enzymatic Total Syntheses of Jorunnamycin A, Saframycin A, and N-Fmoc Saframycin Y3.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b07161
Abstract: The antitumor tetrahydroisoquinoline (THIQ) alkaloids share a common pentacyclic scaffold that is biosynthesized by nonribosomal peptide synthetases involving unique enzymatic Pictet-Spengler cyclizations. Herein we report concise and divergent chemo-enzymatic total syntheses of THIQ alkaloids by… read more here.
Keywords: jorunnamycin saframycin; total syntheses; enzymatic total; chemo enzymatic ... See more keywords
Chemo-enzymatic pathways toward pinene-based renewable materials
Sign Up to like & getrecommendations! Published in 2019 at "Green Chemistry"
DOI: 10.1039/c9gc00718k
Abstract: Chemo-enzymatic conversion of underutilized forest-waste products into multi-functional polymers. read more here.
Keywords: pinene based; chemo enzymatic; enzymatic pathways; based renewable ... See more keywords
Chemo-enzymatic synthesis of a levoglucosenone-derived bi-functional monomer and its ring-opening metathesis polymerization in the green solvent Cyrene™
Sign Up to like & getrecommendations! Published in 2020 at "Polymer Chemistry"
DOI: 10.1039/d0py01471k
Abstract: The levoglucosenone-based norbornenes family was extended to include a new bi-functional methacrylate monomer that, upon ROMP in Cyrene™, leads to polymers with pendent methacrylate moieties which can be modified by post-polymerization reactions. read more here.
Keywords: polymerization; chemo enzymatic; enzymatic synthesis; cyrene ... See more keywords
Sustainable chemo-enzymatic synthesis of glycerol carbonate (meth)acrylate from glycidol and carbon dioxide enabled by ionic liquid technologies
Sign Up to like & getrecommendations! Published in 2021 at "Green Chemistry"
DOI: 10.1039/d1gc01096d
Abstract: A sustainable chemo-enzymatic process for producing both glycerol carbonate acrylate and glycerol carbonate methacrylate, as monomers for the preparation of biodegradable plastic materials, has been developed by using ionic liquid technologies. read more here.
Keywords: glycerol carbonate; chemo enzymatic; ionic liquid; sustainable chemo ... See more keywords
Enzymatic and chemo-enzymatic strategies to produce highly valuable chiral amines from biomass with ω-transaminases on 2D zeolites
Sign Up to like & getrecommendations! Published in 2022 at "National Science Review"
DOI: 10.1093/nsr/nwac135
Abstract: Abstract Amino transaminases (ATAs) have been supported on a 2D ITQ-2 zeolite through electrostatic interactions, resulting in a highly stable active biocatalyst to obtain a variety of valuable chiral amines starting from prochiral ketones derived… read more here.
Keywords: valuable chiral; biomass; chiral amines; enzymatic chemo ... See more keywords
Chemo-enzymatic Synthesis of Ester-Linked Docetaxel-Glycoside Conjugate and its Drug Delivery System Using Hybrid-Bio-Nanocapsules Targeted With Trastuzumab and Cetuximab
Sign Up to like & getrecommendations! Published in 2019 at "Natural Product Communications"
DOI: 10.1177/1934578x19858803
Abstract: Synthesis of ester-linked glucoside conjugate of docetaxel, 7-propionyldocetaxel 3''-O-α-D-glucopyranoside, was carried out by chemo-enzymatic procedures. The EE and LE values for hybrid-bio-nanocapsules of 7-propionyldocetaxel 3''-O-α-D-glucopyranoside were much improved rather than those of docetaxel. The hybrid-bio-nanocapsules… read more here.
Keywords: chemo enzymatic; bio nanocapsules; ester linked; nanocapsules targeted ... See more keywords
Efficient Chemo-Enzymatic Flow Synthesis of High Value Amides and Esters
Sign Up to like & getrecommendations! Published in 2020 at "Catalysts"
DOI: 10.3390/catal10080939
Abstract: A flow-based chemo-enzymatic synthesis of selected APIs (i.e., butacaine, procaine and procainamide) has been developed. A bioreactor made of MsAcT, a versatile acyltransferase from Mycobacterium smegmatis, immobilised on glyoxyl–garose, was exploited to efficiently prepare amide… read more here.
Keywords: efficient chemo; chemo enzymatic; flow synthesis; enzymatic flow ... See more keywords