Phosphine–Borane Ligands Induce Chemoselective Activation and Catalytic Coupling of Acyl Chlorides at Palladium
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DOI: 10.1021/acscatal.0c04287
Abstract: Acyl chlorides are highly reactive and widely used substrates in catalytic cross-coupling reactions, but so far, site selectivity over other functional groups has remained an issue. In this work, P... read more here.
Keywords: induce chemoselective; phosphine borane; borane ligands; chemoselective activation ... See more keywords
Palladium-Catalyzed Chemoselective Activation of sp3 vs sp2 C-H Bonds: Oxidative Coupling To Form Quaternary Centers.
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DOI: 10.1021/acscatal.9b00091
Abstract: The oxidative activation of alkyl C-H bonds vs arene C-H bonds with Pd(OAc)2 has been found to be generalizable to a number of nucleophilic substrates allowing the formation of a range of hindered quaternary centers.… read more here.
Keywords: activation; catalyzed chemoselective; chemoselective activation; activation sp3 ... See more keywords