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Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c04287
Abstract: Acyl chlorides are highly reactive and widely used substrates in catalytic cross-coupling reactions, but so far, site selectivity over other functional groups has remained an issue. In this work, P...
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Keywords:
induce chemoselective;
phosphine borane;
borane ligands;
chemoselective activation ... See more keywords
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Published in 2019 at "ACS catalysis"
DOI: 10.1021/acscatal.9b00091
Abstract: The oxidative activation of alkyl C-H bonds vs arene C-H bonds with Pd(OAc)2 has been found to be generalizable to a number of nucleophilic substrates allowing the formation of a range of hindered quaternary centers.…
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Keywords:
activation;
catalyzed chemoselective;
chemoselective activation;
activation sp3 ... See more keywords