Articles with "chemoselective activation" as a keyword



Phosphine–Borane Ligands Induce Chemoselective Activation and Catalytic Coupling of Acyl Chlorides at Palladium

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Published in 2021 at "ACS Catalysis"

DOI: 10.1021/acscatal.0c04287

Abstract: Acyl chlorides are highly reactive and widely used substrates in catalytic cross-coupling reactions, but so far, site selectivity over other functional groups has remained an issue. In this work, P... read more here.

Keywords: induce chemoselective; phosphine borane; borane ligands; chemoselective activation ... See more keywords
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Palladium-Catalyzed Chemoselective Activation of sp3 vs sp2 C-H Bonds: Oxidative Coupling To Form Quaternary Centers.

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Published in 2019 at "ACS catalysis"

DOI: 10.1021/acscatal.9b00091

Abstract: The oxidative activation of alkyl C-H bonds vs arene C-H bonds with Pd(OAc)2 has been found to be generalizable to a number of nucleophilic substrates allowing the formation of a range of hindered quaternary centers.… read more here.

Keywords: activation; catalyzed chemoselective; chemoselective activation; activation sp3 ... See more keywords