Regio- and chemoselective hydroamination of unactivated alkenes with anthranils via NiH-catalysis.
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DOI: 10.1039/d2cc07052a
Abstract: A NiH-catalyzed polarity-reversed hydroamination of β,γ-, γ,δ- and δ,ε-unsaturated alkenes with electrophilic anthranils was developed. This reaction proceeds in a highly regio- and chemoselective manner to afford γ, δ and ε-arylamines bearing a carbonyl or… read more here.
Keywords: hydroamination unactivated; regio chemoselective; hydroamination; chemoselective hydroamination ... See more keywords