Chemoselective N−H insertion catalyzed by a de novo carbene transferase
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DOI: 10.1002/bab.1924
Abstract: The ability to perform organic reactions with chemoselectivity is of critical importance in synthesis. Recently, we reported that a de novo carbene transferase, a tetra‐α‐helical c‐type heme‐containing protein, C45, is proficient at N−H insertion reactions,… read more here.
Keywords: chemoselective insertion; insertion; carbene transferase; novo carbene ... See more keywords