Chemoselective Primary Amination of Aryl Boronic Acids by PIII/PV═O-Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO.
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DOI: 10.1021/jacs.2c02922
Abstract: A catalytic approach to intercept the transient HNO for a chemoselective primary amination of arylboronic acids is reported. A phosphetane-based catalyst operating within PIII/PV═O redox cycling is shown to capture HNO, generated in situ by… read more here.
Keywords: chemoselective primary; transient; primary amination; hno ... See more keywords