Visible-Light Paternò-Büchi Reaction for Lipidomic Profiling at Detailed Structure Levels.
Sign Up to like & getrecommendations! Published in 2023 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.3c00085
Abstract: The Paternò-Büchi (PB) derivatization of carbon-carbon double bond (C═C) has been increasingly employed with tandem mass spectrometry to analyze unsaturated lipids. It enables the discovery of altered or uncanonical lipid desaturation metabolism, which would be… read more here.
Keywords: patern chi; reaction; chi reaction; light patern ... See more keywords
Transposed Paternò-Büchi Reaction.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.6b05936
Abstract: A complementary strategy of utilizing ππ* excited state of alkene instead of nπ* excited state of the carbonyl chromophore in a "transposed Paternò-Büchi" reaction is evaluated with atropisomeric enamides as the model system. Based on… read more here.
Keywords: chi reaction; excited state; reaction; transposed patern ... See more keywords