Photochemical Deracemization of Chiral Alkenes via Triplet Energy Transfer.
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DOI: 10.1021/jacs.2c02511
Abstract: A visible-light-mediated, enantioselective approach to axially chiral alkenes is described. Starting from a racemic mixture, a major alkene enantiomer is formed due to selective triplet energy transfer from a catalytically active chiral sensitizer. A catalyst… read more here.
Keywords: triplet energy; chiral alkenes; energy transfer;