Asymmetric Azide-Alkyne Cycloaddition with Ir(I)/Squaramide Cooperative Catalysis: Atroposelective Synthesis of Axially Chiral Aryltriazoles.
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DOI: 10.1021/jacs.2c02563
Abstract: An Ir(I)/squaramide cooperative catalytic strategy for atroposelective synthesis of axially chiral aryltriazoles has been developed for the first time. Diverse structurally novel aryltriazole skeletons that cannot be accessed by traditional click reactions were synthesized in… read more here.
Keywords: chiral aryltriazoles; squaramide cooperative; axially chiral; synthesis axially ... See more keywords