Nazarov Cyclization Entry to Chiral Bicyclo[5.3.0]decanoid Building Blocks and Its Application to Formal Synthesis of (-)-Englerin A.
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DOI: 10.1021/acs.orglett.7b02428
Abstract: A divergent entry to the chiral bicyclo[5.3.0]decane skeletons relevant to sesqui- and higher terpenoids has been achieved. Its usefulness was demonstrated by formal synthesis of a guaiane sesquiterpenoid (-)-englerin A. The key reactions are (i)… read more here.
Keywords: bicyclo; formal synthesis; chiral bicyclo; nazarov cyclization ... See more keywords