Directing the handedness of helical nanofilaments confined in nanochannels using axially chiral binaphthyl dopants.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.9b20696
Abstract: Deracemization of twisted structures at the nanoscale is of prime importance in technologies used to achieve separation of enantiomers. In this work, we demonstrate control of the handedness of semi-crystalline modulated helical nanofilaments (HNFmods) formed… read more here.
Keywords: nanofilaments confined; helical nanofilaments; directing handedness; handedness helical ... See more keywords
A chiral binaphthyl-based coordination polymer as an enantioselective fluorescence sensor.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d1cc06872e
Abstract: A fluorescent, chiral coordination polymer (CP) with a novel topology has been synthesised using a dipyridyl ligand derived from 1,1'-bi-2-naphthol (BINOL). Enantioselectivity ratios up to 2.61 were obtained in fluorescence sensing studies with chiral analytes. read more here.
Keywords: chiral binaphthyl; coordination polymer; coordination; binaphthyl based ... See more keywords