A novel, C2-symmetric, chiral bis-cyclosulfinamide-olefin tridentate ligand in Rh-catalyzed asymmetric 1,4-additions
Sign Up to like & getrecommendations! Published in 2018 at "Tetrahedron Letters"
DOI: 10.1016/j.tetlet.2018.06.008
Abstract: Abstract A C2-symmetric, chiral bis-cyclosulfinamide-olefin ligand composed of two 1-oxo-2,3-dihydro-1,2-benzisothiazole moieties with rigid skeletons and a conformationally flexible butenylene chain is disclosed for the first time. HRMS and 1H NMR analyses verify that the in… read more here.
Keywords: cyclosulfinamide olefin; symmetric chiral; chiral bis; tridentate ligand ... See more keywords
Synthesis of Axially Chiral 1,2,3-Triazol-5-ylidene–Au(I) Complex and Its Application in Enantioselective [2 + 2] Cycloaddition of Alleneamides with Alkenes
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00524
Abstract: A series of axially chiral bis-1,2,3-triazol-5-ylidene Au(I) complexes (R)-8a–g and one mono-1,2,3-triazol-5-ylidene Au(I) complex (R)-9a were prepared from commercially available (R)-binaphthyl-2,2-diamine (BINAM) compound, in which, transmetalation of bis(MIC)-bis[Ag(I)] intermediates to the corresponding Au(I) complexes were… read more here.
Keywords: triazol ylidene; ylidene complex; chiral bis; ylidene ... See more keywords
Synthesis and Characterization of Enantiopure Chiral Bis NHC-Stabilized Edge-Shared Au10 Nanocluster with Unique Prolate Shape.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c11857
Abstract: Herein we report the first chiral Au10 nanoclusters stabilized by chiral bis N-heterocyclic carbene (bisNHC) ligands. ESI-MS and single-crystal X-ray crystallography confirmed the molecular formula to be [Au10(bisNHC)4Br2](O2CCF3)2. The chiral Au10 nanocluster adopts a linear… read more here.
Keywords: chiral bis; edge shared; prolate shape; au10 nanocluster ... See more keywords
Direct catalytic enantioselective Mannich-type reaction of α,α-dithioacetonitriles with imines using chiral bis(imidazoline)-Pd complexes.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc03307a
Abstract: The first highly enantioselective reaction of α,α-dithioacetonitriles with imines has been developed. Good yields and enantioselectivity were observed for the reaction of various imines using chiral bis(imidazoline) catalysts. The obtained products can be converted into… read more here.
Keywords: reaction dithioacetonitriles; chiral bis; reaction; imines using ... See more keywords
Chiral bis(benzo[1,2-b:4,3-b′]dithiophene) atropisomers: experimental and theoretical investigations of the stereochemical and chiroptical properties
Sign Up to like & getrecommendations! Published in 2021 at "New Journal of Chemistry"
DOI: 10.1039/d1nj03248h
Abstract: Conformational chirality is a feature that may arise from the presence of a hindered rotation around a single bond that corresponds to a stereogenic axis. read more here.
Keywords: benzo dithiophene; atropisomers experimental; bis benzo; chiral bis ... See more keywords
Chiral Bis(tetrathiafulvalene)-1,2-cyclohexane-diamides
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27206926
Abstract: Chiral bis(TTF) diamides have been obtained in good yields (54–74%) from 1,2-cyclohexane-diamine and the corresponding TTF acyl chlorides. The (R,R)-1 and (S,S)-1 enantiomers have been characterized by circular dichroism and the racemic form by single-crystal… read more here.
Keywords: bis tetrathiafulvalene; cyclohexane diamides; ttf; chiral bis ... See more keywords