Chiral-Bisphosphine-Catalyzed Asymmetric Staudinger/Aza-Wittig Reaction: Development, Mechanism Study, and Synthetic Application
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DOI: 10.1055/s-0043-1775038
Abstract: The enantioselective desymmetrization of 2,2-disubstituted cyclohexane-1,3-diones has been realized through an unprecedented chiral-bisphosphine-catalyzed asymmetric Staudinger/aza-Wittig reaction. The key to this work’s success lies in utilizing an electronically rich and sterically hindered chiral bisphosphine reagent, namely… read more here.
Keywords: staudinger aza; bisphosphine catalyzed; asymmetric staudinger; chiral bisphosphine ... See more keywords