Cu2O/Cu Chiral Catalysts for Highly Selective Solar‐Assisted CO2‐to‐CO Electroreduction
Sign Up to like & getrecommendations! Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202508577
Abstract: The intrinsic spin control capabilities of chiral materials help regulate the spin states of charge carriers, suppressing singlet‐state byproducts like H2 and HCOOH while enhancing the Faradaic efficiency (FE) for CO. To induce strong chirality… read more here.
Keywords: solar assisted; chiral catalysts; cu2o chiral; catalysts highly ... See more keywords
l-proline modulated zirconium metal organic frameworks: Simple chiral catalysts for the aldol addition reaction
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2018.06.013
Abstract: Abstract Three l -proline modulated zirconium based MOFs denoted as UiO-66, Zr-NDC (NDC = 2,6-Naphthalenedicarboxylate) and UiO-67 were synthesized, characterized and explored as heterogeneous catalyst in diastereoselective aldol addition reactions between 4-nitrobenzaldehyde and linear/cyclic ketones. Upon l… read more here.
Keywords: chiral catalysts; proline modulated; proline; modulated zirconium ... See more keywords
Enantioselective Radical Reactions Using Chiral Catalysts.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.1c00582
Abstract: Benefiting from the impressive increase in fundamental knowledge, the last 20 years have shown a continuous burst of new ideas and consequently a plethora of new catalytic methods for enantioselective radical reactions. This review aims… read more here.
Keywords: chiral catalysts; review; using chiral; radical reactions ... See more keywords
Chiral π-Cu(II) Catalysts for the Enantioselective α-Amination of N-Acyl-3,5-dimethylpyrazoles.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c03249
Abstract: We report the highly enantioselective α-amination of N-acyl-3,5-dimethylpyrazoles with dialkyl azodicarboxylates, catalyzed by in situ generated π-Cu(II) complexes that consist of Cu(OTf)2 and N-(5H-dibenzo[a,d][7]annulen-5-yl)-l-alanine-derived amides, to give the corresponding products as d-α-amino acid derivatives (up… read more here.
Keywords: chiral catalysts; acyl dimethylpyrazoles; amination acyl; enantioselective amination ... See more keywords
Insights on Absolute and Relative Stereocontrol in Stereodivergent Cooperative Catalysis.
Sign Up to like & getrecommendations! Published in 2020 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b13962
Abstract: An increasing number of examples demonstrate that the use of two mutually compatible chiral catalysts in one-pot conditions can help realize the long-cherished goal of simultaneous control of absolute and relative configurations in asymmetric catalysis.… read more here.
Keywords: chiral catalysts; absolute relative; catalysis; insights absolute ... See more keywords
Heterochiral coupling to bilateral β-turn structured azapeptides bearing two remote chiral centers
Sign Up to like & getrecommendations! Published in 2024 at "Nature Communications"
DOI: 10.1038/s41467-024-53744-x
Abstract: Enantioselective synthesis governed by chiral catalysts has been extensively developed, but that without any chiral auxiliaries or chiral catalysts is rare, particularly when remote stereogenic centers are involved. Here we report an enantioselectivity of heterochiral… read more here.
Keywords: enantioselective synthesis; turn; chiral catalysts; chiral centers ... See more keywords