Enantioselective Intermolecular C–H Amination Directed by a Chiral Cation
Sign Up to like & getrecommendations! Published in 2021 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c05206
Abstract: The enantioselective amination of C(sp3)–H bonds is a powerful synthetic transformation yet highly challenging to achieve in an intermolecular sense. We have developed a family of anionic variants of the best-in-class catalyst for Rh-catalyzed C–H… read more here.
Keywords: enantioselective intermolecular; cation; intermolecular amination; amination directed ... See more keywords
Enantioselective remote C–H activation directed by a chiral cation
Sign Up to like & getrecommendations! Published in 2020 at "Science"
DOI: 10.1126/science.aba1120
Abstract: Asymmetry on the plus side Numerous positively charged metal catalysts have been paired with chiral negative ions to select for just one of two mirror-image products. Genov et al. now report a potentially general strategy… read more here.
Keywords: metal catalysts; metal; chiral cation; ligand ... See more keywords