Magnetic 3d-4f Chiral Clusters Showing Multimetal Site Magneto-Chiral Dichroism.
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DOI: 10.1021/jacs.2c03049
Abstract: Here, we report the molecular self-assembly of hydroxido-bridged {Ln5Ni6} ((Ln3+ = Dy3+, Y3+) metal clusters by the reaction of enantiopure chiral ligands, namely, (R/S)-(2-hydroxy-3-methoxybenzyl)-serine), with NiII and LnIII precursors. Single-crystal diffraction analysis reveals that these… read more here.
Keywords: chiral dichroism; clusters showing; magneto chiral; multimetal site ... See more keywords
Local-Site Dependency of Magneto-Chiral Dichroism in Enantiopure One-Dimensional Copper(II)–Chromium(III) Coordination Polymers
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DOI: 10.7566/jpsj.88.093708
Abstract: Magneto-chiral dichroism (MChD) is a nonreciprocal directional dichroism emerged by applying a magnetic field to chiral materials, which provides a clear distinction between light propagating paral... read more here.
Keywords: site dependency; dichroism; chiral dichroism; local site ... See more keywords