Enantioselective Folding of Enynes by Gold(I) Catalysts with a Remote C2-Chiral Element.
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.9b06326
Abstract: Chiral gold(I) catalysts have been designed based on a modified JohnPhos ligand with a distal C2-2,5-diarylpyrrolidine that creates a tight binding cavity. The C2-chiral element is close to where the C-C bond formation takes place… read more here.
Keywords: enantioselective folding; chiral element; gold catalysts;
BINOL as a chiral element in mechanically interlocked molecules
Sign Up to like & getrecommendations! Published in 2022 at "Beilstein Journal of Organic Chemistry"
DOI: 10.3762/bjoc.18.53
Abstract: In this minireview we present the use of the axially chiral 1,1'-binaphthyl-2,2'-diol (BINOL) unit as a stereogenic element in mechanically interlocked molecules (MIMs). We describe the synthesis and properties of such BINOL-based chiral MIMs, together… read more here.
Keywords: binol chiral; chiral element; mechanically interlocked; element mechanically ... See more keywords