Articles with "chiral environment" as a keyword



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A posteriori error analysis for the scattering by obstacles in a homogeneous chiral environment

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Published in 2019 at "Applied Numerical Mathematics"

DOI: 10.1016/j.apnum.2018.08.017

Abstract: Abstract In this paper we consider the scattering of time-harmonic electromagnetic wave propagation in a homogeneous chiral environment by obstacles. The model is simplified to a two-dimensional scattering problem, and is formulated as a boundary… read more here.

Keywords: posteriori error; error; chiral environment; homogeneous chiral ... See more keywords
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Dirhodium(II)/Phosphine Catalyst with Chiral Environment at Bridging Site and Its Application in Enantioselective Atropisomer Synthesis

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Published in 2023 at "ACS Central Science"

DOI: 10.1021/acscentsci.2c01207

Abstract: A dirhodium(II)/phosphine catalyst with a chiral environment at the bridging site was developed for the asymmetric arylation of phenanthrene-9,10-diones with arylboronic acids. In contrast to the classic chiral bridging carboxylic acid (or derivatives) ligand strategy… read more here.

Keywords: phosphine; phosphine catalyst; dirhodium; dirhodium phosphine ... See more keywords

Induced circular dichroism of monoatomic anions: silica-assisted the transfer of chiral environment from molecular assembled nanohelices to halide ions.

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Published in 2018 at "Chemical communications"

DOI: 10.1039/c8cc05449e

Abstract: We demonstrate the first example of induced CD of monoatomic anions. This was detected using chirally-arranged molecular assemblies of non-chiral cationic gemini surfactants (16-2-16) with monoatomic anions stabilized with silica-coating. Furthermore, we have also achieved… read more here.

Keywords: chiral environment; transfer chiral; circular dichroism; monoatomic anions ... See more keywords