Structural Control and Chiroptical Response in Intrinsically Tetra- and Pentanuclear Chiral Gold Clusters.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c00256
Abstract: Controlling the synthesis of chiral metal clusters in the aspects of nuclearity number, metal-metal interaction, and spatial arrangement of metal atoms is crucial for establishing the correlation of detailed structural factors with chiroptical activity. Herein,… read more here.
Keywords: gold clusters; chiral gold; chiroptical response; gold ... See more keywords
Selectively Regulating the Chiral Morphology of Amino Acid-Assisted Chiral Gold Nanoparticles with Circularly Polarized Light.
Sign Up to like & getrecommendations! Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c22191
Abstract: Chiral nanomaterials have attracted increasing attention due to their versatile optical properties. Although circularly polarized (CP) light can serve as an inducer, it has negligible effects because of the short lifetime of the plasmonic states.… read more here.
Keywords: polarized light; assisted chiral; acid assisted; amino acid ... See more keywords
Chiral gold(III) complexes: speciation, in vitro, and in vivo anticancer profile.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc03081k
Abstract: Emerging synthetic development of chiral gold(III) complexes has prompted new opportunities in catalysis and material science with limited utility in biomedicine. Here, we demonstrate potential chemotherapeutic capability of [C^N]Au(III)Cl(R-DuPhos) (1-7) complexes, containing 1,2-bis[(2R,5R)-2,5-dialkylphospholano]benzene, which shows… read more here.
Keywords: iii complexes; iii; chiral gold; anticancer ... See more keywords