Guest-Driven Self-Assembly and Chiral Induction of Photofunctional Lanthanide Tetrahedral Cages.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c00760
Abstract: Chiral luminescent lanthanide-organic cages have many potential applications in enantioselective recognition, sensing, and asymmetric catalysis. However, due to the paucity of structures and their limited cavities, host-guest chemistry with lanthanide-organic cages has remained elusive so… read more here.
Keywords: chiral induction; driven self; guest driven; self assembly ... See more keywords
Enantioseparation and chiral induction in Ag29 nanoclusters with intrinsic chirality†
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DOI: 10.1039/c9sc05299b
Abstract: The optical activity of a metal nanocluster (NC) is induced either by an asymmetric arrangement of constituents or by a dissymmetric field of a chiral ligand layer. Herein, we unveil the origin of chirality in… read more here.
Keywords: intrinsic chirality; chirality; enantioseparation chiral; ag29 ... See more keywords
Asymmetric Induction and Amplification in Stereodynamic Catalytic Systems by Noncovalent Interactions
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DOI: 10.1055/a-1274-2777
Abstract: The local transmission of chiral information by noncovalent interactions is one of the most fundamental processes broadly found in nature, i.e. in complex biochemical systems. This review summarizes our accomplishments in investigating chiral induction in… read more here.
Keywords: induction amplification; noncovalent interactions; asymmetric induction; chiral induction ... See more keywords
Kinetic Investigations on the Chiral Induction by Amino Acids in Porphyrin J-Aggregates
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DOI: 10.3390/ijms24021695
Abstract: The self-assembling kinetics of the 5,10,15,20-tetrakis(4-sulfonato-phenyl)porphyrin (TPPS4) into nano-tubular J-aggregates under strong acidic condition and in the presence of amino acids as templating chiral reagents have been investigated through UV/Vis spectroscopy. The ability of the… read more here.
Keywords: amino acids; kinetic investigations; investigations chiral; spectroscopy ... See more keywords