Dirhodium(ii)-catalysed cycloisomerization of azaenyne: rapid assembly of centrally and axially chiral isoindazole frameworks
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DOI: 10.1039/d1sc04961e
Abstract: Described herein is a dirhodium(ii)-catalyzed asymmetric cycloisomerization reaction of azaenyne through a cap-tether synergistic modulation strategy, which represents the first catalytic asymmetric cycloisomerization of azaenyne. This reaction is highly challenging because of its inherent strong… read more here.
Keywords: cycloisomerization azaenyne; dirhodium; cycloisomerization; chiral isoindazole ... See more keywords