A pair of 3D enantiotopic zinc(ii) complexes based on two asymmetric achiral ligands.
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DOI: 10.1039/c7dt03205f
Abstract: Enantiomorphism and enantioselectivity are critical in biology and many other applications. Herein, we report two 3D chiral MOFs {[Zn6(MIDPPA)3(1,2,4-btc)3(NO2)3(H2O)3](H2O)7}n (1L and 1R) based on achiral ligands with high enantiomeric excess and a novel topological type.… read more here.
Keywords: enantiotopic zinc; zinc complexes; chiral mofs; complexes based ... See more keywords