Half-sandwich chiral rare-earth metal complexes with linked tridentate amido-indenyl ligand: synthesis, characterization, and catalytic properties for intramolecular hydroamination
Sign Up to like & getrecommendations! Published in 2017 at "RSC Advances"
DOI: 10.1039/c6ra26537e
Abstract: The enantioselective intramolecular hydroamination of alkenes with free amines has been a touchstone reaction in the development of many new chiral rare-earth (RE) metal complexes. In this article, we describe the synthesis and characterization of… read more here.
Keywords: chiral rare; rare earth; metal complexes; earth metal ... See more keywords
A new chiral rare-earth organic framework constructed by tartaric acid: synthesis, structural, thermal investigations and optical properties.
Sign Up to like & getrecommendations! Published in 2022 at "Acta crystallographica. Section C, Structural chemistry"
DOI: 10.1107/s2053229622004302
Abstract: Hydrothermal reactions of rare-earth cerium with L-tartaric acid afford a new coordination polymer, namely, poly[[triaqua(μ4-L-tartrato)cerium(III)] chloride], {[Ce(C4H4O6)(H2O)3]Cl}n, (1). The structure was determined by single-crystal X-ray diffraction analysis and further characterized by IR and UV-Vis spectroscopy,… read more here.
Keywords: chiral rare; tartaric acid; ray diffraction; new chiral ... See more keywords