Multinuclear nickel(II) complexes with chiral schiff base ligand
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.119798
Abstract: Abstract Herein we report three chiral, hierarchal mono-, tetra-, and hexa-nuclear nickel complexes that were formed via controlled self-aggregation based on ancillary ligands H3L1 (2,6-bis[(2,3-dihydro-1H-2-indenol)imine]-4-bromophenol) and H3L2 (2,6-bis[(2,3-dihydro-1H-2-indenol)imine]-4-tert-butylphenol). Stoichiometric control of the metal precursor and… read more here.
Keywords: nickel; multinuclear nickel; chiral schiff; nickel complexes ... See more keywords
Synthesis, characterization and crystal structures of half-sandwich ruthenium complexes with bidentate chiral Schiff-base ligands
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121129
Abstract: Abstract Condensation of salicylaldehyde or 5-nitrosalicylaldehyde with (S)-(+)-2-amino-3-methyl-1-butanol in refluxing ethanol afforded the chiral Schiff-base ligands (S)-N-(1-hydroxymethylisobutyl)salicylidene (HL1*) and (S)-N-1-hydroxymethylisobutyl-5-nitrosalicylidene (HL2*), respectively. Similarly, reaction of 3,5-di-tert-butylsalicylaldehyde or 3,5-dibromosalicylaldehyde with (R)-(+)-α-methylbenzylamine gave the chiral Schiff base… read more here.
Keywords: base ligands; chiral schiff; sandwich ruthenium; half sandwich ... See more keywords
Hemi-synthesis, in-vitro and in-silico bioactivities of new chiral-Schiff bases and benzodiazepine derivatives from Ammodaucus leucotrichus(S)-perillaldehyde
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2021.130690
Abstract: Abstract A new series of benzodiazepines and chiral Schiff bases have been prepared by an in situ condensation of (S)-(-)-perillaldehyde, occurring naturally in the essential oil of Ammodaucus leucotrichus subsp. Leucotrichus, with various amines, hydrazines,… read more here.
Keywords: hemi synthesis; ammodaucus leucotrichus; schiff bases; chiral schiff ... See more keywords
Synthesis of Chiral Schiff Base Metal Complex Inducing CD and Elucidation of Structure of Adsorption on Surface of Gold Nanoparticles
Sign Up to like & getrecommendations! Published in 2017 at "Informs Journal on Computing"
DOI: 10.4236/ijoc.2017.72013
Abstract: We have prepared supramolecular systems of chiral Schiff base Ni(II), Cu(II), Zn(II) complexes and colloidal gold nanoparticles (AuNP) of 10 nm diameters. They demonstrated that direct adsorption of chiral Schiff base metal complex on the… read more here.
Keywords: chiral schiff; base metal; gold nanoparticles; schiff base ... See more keywords