Chiral Self-Sorting Process With C2 Symmetric Bisimidazoline Ligands.
Sign Up to like & getrecommendations! Published in 2024 at "Chirality"
DOI: 10.1002/chir.23720
Abstract: We have studied the coordination chemistry of chiral imidazoline-based C2-symmetric ligands with zinc (II) and copper (II). Two types of bisimidazoline ligands were studied, one with the free amine (BIM-H) and the other with the… read more here.
Keywords: bisimidazoline; self sorting; process symmetric; bisimidazoline ligands ... See more keywords
Chiral Self-Assembly of Twisted Prisms, Cuboids, and Polyhedral Capped Cages with Tartrate Ligands.
Sign Up to like & getrecommendations! Published in 2024 at "Small"
DOI: 10.1002/smll.202406134
Abstract: Homochiral triangular prisms, cuboid cages, and capped polyhedral cages are successfully synthesized via coordination-driven self-assembly. Typical tartrate ligands demonstrated notable torsional flexibility and variable coordination numbers, allowing for diverse coordination patterns, including saturated chelation and… read more here.
Keywords: tartrate ligands; self assembly; chiral self; assembly twisted ... See more keywords
Origin of vacuum-assisted chiral self-assembly of cellulose nanocrystals.
Sign Up to like & getrecommendations! Published in 2020 at "Carbohydrate polymers"
DOI: 10.1016/j.carbpol.2020.116459
Abstract: To produce functional cellulose nanocrystal (CNC) films with desirable optical and mechanical properties, it is critical to understand and control the chiral self-assembly of CNCs during solvent removal. Here, the formation mechanism of CNC chiral… read more here.
Keywords: cnc; self assembly; filter paper; chiral self ... See more keywords
Chiral Self-Assembly of Zinc and Magnesium Porphyrins with Enantiopure Cyclohexanohemicucurbiturils in Solution and in Solid State.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c04969
Abstract: Chiral self-assembled supramolecular networks offer great potential for new chiral materials. We report the predictable self-assembly of metalloporphyrins with chiral cyclohexanohemicucurbit[n]urils (cycHC[6] and cycHC[8]), where cycHC[n] chirality is transferred to achiral porphyrins in solution and… read more here.
Keywords: solution; chiral self; self; solid state ... See more keywords
Conformational Selectivity and Chiral Self-Assembly Structures of Crown Ethers on Metal Surfaces.
Sign Up to like & getrecommendations! Published in 2025 at "ACS nano"
DOI: 10.1021/acsnano.4c15062
Abstract: Crown ethers (CEs), macrocyclic polyethers, have attracted significant attention in supramolecular chemistry. It is known that they have many isomers due to their flexibility. It is challenging to select some exact conformation and tune the… read more here.
Keywords: assembly structures; crown ethers; self assembly; chiral self ... See more keywords
Anthracenemethyl Glycosides as Supramolecular Synthons for Chiral Self-Assembly and as Probes in Cell Imaging
Sign Up to like & getrecommendations! Published in 2023 at "ACS Omega"
DOI: 10.1021/acsomega.3c00767
Abstract: Chiral self-assembly of molecules warrants optimal structural features of synthons that promote formation of such self-assembled structures. A polyaromatic moiety coupled with hydrophilic, chiral-rich carbohydrates leads to segmentation of the regions and the self-assembly to… read more here.
Keywords: cell; self assembly; supramolecular structures; chiral self ... See more keywords
Chiral self-sorting process in the self-assembly of homochiral coordination cages from axially chiral ligands
Sign Up to like & getrecommendations! Published in 2018 at "Communications Chemistry"
DOI: 10.1038/s42004-018-0020-4
Abstract: Chiral self-sorting is a phenomenon wherein racemic components are spontaneously sorted into homo- or heterochiral molecular assemblies through chiral discrimination between the components. Chiral self-sorting may be related to biological molecular systems where chiral biomolecules… read more here.
Keywords: self sorting; self assembly; chiral self; self ... See more keywords
Adjustable chiral self-sorting and self-discriminating behaviour between diamond-like Tröger's base-linked cryptands.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc03577j
Abstract: Two isomers of Tröger's base-linked cryptands 5a and 5b were synthesized, and both of them have two chiral N-centers, exhibiting rare diamond-like scaffolds. Particularly, when growing from the solution of rac-5a, a single enantiomer RNRN-5a… read more here.
Keywords: linked cryptands; base linked; ger base; chiral self ... See more keywords
Chiral self-sorting behaviour of [2.2]paracyclophane-based bis(pyridine) ligands
Sign Up to like & getrecommendations! Published in 2019 at "Organic Chemistry Frontiers"
DOI: 10.1039/c9qo00155g
Abstract: [2.2]Paracyclophane-based bis(pyridine) ligands form dinuclear complexes upon coordination to palladium(ii) ions, however, with distinct differences concerning their chiral self-sorting ability. read more here.
Keywords: self sorting; bis pyridine; based bis; chiral self ... See more keywords
Helicity-driven chiral self-sorting supramolecular polymerization with Ag+: right- and left-helical aggregates
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc06413d
Abstract: The study of chiral self-sorting is extremely important for understanding biological systems and for developing applications for the biomedical field. In this study, we attempted unprecedented chiral self-sorting supramolecular polymerization accompanying helical inversion with Ag+… read more here.
Keywords: self; supramolecular polymerization; chiral self; helicity ... See more keywords
Odd-even effect in chiral side-chain cyanobiphenyl block copolymer assemblies prepared by polymerization-induced chiral self-assembly.
Sign Up to like & getrecommendations! Published in 2024 at "Nanoscale"
DOI: 10.1039/d4nr02532f
Abstract: The precise control of the chirality of polymer assemblies is a challenge faced by scientists and has received significant attention in recent years. In this study, we employed the polymerization-induced chiral self-assembly (PICSA) method to… read more here.
Keywords: chiral side; self assembly; chiral self; side chain ... See more keywords