Origin of vacuum-assisted chiral self-assembly of cellulose nanocrystals.
Sign Up to like & getrecommendations! Published in 2020 at "Carbohydrate polymers"
DOI: 10.1016/j.carbpol.2020.116459
Abstract: To produce functional cellulose nanocrystal (CNC) films with desirable optical and mechanical properties, it is critical to understand and control the chiral self-assembly of CNCs during solvent removal. Here, the formation mechanism of CNC chiral… read more here.
Keywords: cnc; self assembly; filter paper; chiral self ... See more keywords
Anthracenemethyl Glycosides as Supramolecular Synthons for Chiral Self-Assembly and as Probes in Cell Imaging
Sign Up to like & getrecommendations! Published in 2023 at "ACS Omega"
DOI: 10.1021/acsomega.3c00767
Abstract: Chiral self-assembly of molecules warrants optimal structural features of synthons that promote formation of such self-assembled structures. A polyaromatic moiety coupled with hydrophilic, chiral-rich carbohydrates leads to segmentation of the regions and the self-assembly to… read more here.
Keywords: cell; self assembly; supramolecular structures; chiral self ... See more keywords
Chiral self-sorting process in the self-assembly of homochiral coordination cages from axially chiral ligands
Sign Up to like & getrecommendations! Published in 2018 at "Communications Chemistry"
DOI: 10.1038/s42004-018-0020-4
Abstract: Chiral self-sorting is a phenomenon wherein racemic components are spontaneously sorted into homo- or heterochiral molecular assemblies through chiral discrimination between the components. Chiral self-sorting may be related to biological molecular systems where chiral biomolecules… read more here.
Keywords: self sorting; self assembly; chiral self; self ... See more keywords
Adjustable chiral self-sorting and self-discriminating behaviour between diamond-like Tröger's base-linked cryptands.
Sign Up to like & getrecommendations! Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc03577j
Abstract: Two isomers of Tröger's base-linked cryptands 5a and 5b were synthesized, and both of them have two chiral N-centers, exhibiting rare diamond-like scaffolds. Particularly, when growing from the solution of rac-5a, a single enantiomer RNRN-5a… read more here.
Keywords: linked cryptands; base linked; ger base; chiral self ... See more keywords
Chiral self-sorting behaviour of [2.2]paracyclophane-based bis(pyridine) ligands
Sign Up to like & getrecommendations! Published in 2019 at "Organic Chemistry Frontiers"
DOI: 10.1039/c9qo00155g
Abstract: [2.2]Paracyclophane-based bis(pyridine) ligands form dinuclear complexes upon coordination to palladium(ii) ions, however, with distinct differences concerning their chiral self-sorting ability. read more here.
Keywords: self sorting; bis pyridine; based bis; chiral self ... See more keywords
Helicity-driven chiral self-sorting supramolecular polymerization with Ag+: right- and left-helical aggregates
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc06413d
Abstract: The study of chiral self-sorting is extremely important for understanding biological systems and for developing applications for the biomedical field. In this study, we attempted unprecedented chiral self-sorting supramolecular polymerization accompanying helical inversion with Ag+… read more here.
Keywords: self; supramolecular polymerization; chiral self; helicity ... See more keywords
Chiral Self-sorting in Cage-like Compounds
Sign Up to like & getrecommendations! Published in 2020 at "Chemistry Letters"
DOI: 10.1246/cl.200477
Abstract: Chiral self-sorting in cage-like compounds is drawing increasing attention in recent years. It is of great importance in controlling the chirality of the formed cages and their chirality related pr... read more here.
Keywords: self sorting; cage like; chiral self; sorting cage ... See more keywords
Biomimetic Self-Assembled Chiral Inorganic Nanomaterials: A New Strategy for Solving Medical Problems
Sign Up to like & getrecommendations! Published in 2022 at "Biomimetics"
DOI: 10.3390/biomimetics7040165
Abstract: The rapid expansion of the study of chiral inorganic structures has led to the extension of the functional boundaries of inorganic materials. Nature-inspired self-assembled chiral inorganic structures exhibit diverse morphologies due to their high assembly… read more here.
Keywords: chiral inorganic; chiral self; self assembled; assembled chiral ... See more keywords