Chiral spirosiladiphosphines: ligand development and applications in Rh-catalyzed asymmetric hydrosilylation/cyclization of 1,6-enynes with enhanced reactivity
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DOI: 10.1039/d2sc06349b
Abstract: Spirodiphosphines have been successfully applied in various asymmetric catalytic transformations. However, controlling the coordinating conformations by the direct displacement of the spiro atom remains elusive. Herein, we report the application of Si-centered spirodiphosphine (Si-SDP) ligands… read more here.
Keywords: chiral spirosiladiphosphines; hydrosilylation cyclization; reactivity; cyclization enynes ... See more keywords